(2R,3S,4R,5R,6R)-5-Amino-2-azidomethyl-6-methoxy-tetrahydro-pyran-3,4-diol

Base Information

Chemical Name:(2R,3S,4R,5R,6R)-5-Amino-2-azidomethyl-6-methoxy-tetrahydro-pyran-3,4-diol
CAS No.:70008-11-6
Molecular Formula:C₇H₁₄N₄O₄
Molecular Weight:218.213
Hs Code.:

Synonyms:(2R,3S,4R,5R,6R)-5-Amino-2-azidomethyl-6-methoxy-tetrahydro-pyran-3,4-diol

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Chemical Property of (2R,3S,4R,5R,6R)-5-Amino-2-azidomethyl-6-methoxy-tetrahydro-pyran-3,4-diol

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Technology Process of (2R,3S,4R,5R,6R)-5-Amino-2-azidomethyl-6-methoxy-tetrahydro-pyran-3,4-diol

There total 1 articles about (2R,3S,4R,5R,6R)-5-Amino-2-azidomethyl-6-methoxy-tetrahydro-pyran-3,4-diol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

: 804557-83-3
Toluene-4-sulfonic acid (2R,3S,4R,5R,6R)-3,4-dihydroxy-6-methoxy-5-(2,2,2-trifluoro-acetylamino)-tetrahydro-pyran-2-ylmethyl ester

: 70008-11-6
(2R,3S,4R,5R,6R)-5-Amino-2-azidomethyl-6-methoxy-tetrahydro-pyran-3,4-diol

Guidance literature:: Toluene-4-sulfonic acid (2R,3S,4R,5R,6R)-3,4-dihydroxy-6-methoxy-5-(2,2,2-trifluoro-acetylamino)-tetrahydro-pyran-2-ylmethyl ester; With sodium azide; In water; acetone; Heating;

With sodium hydroxide; at 20 ℃; for 0.333333h;
DOI:10.1021/ja045147v

Reference yield:

: 3218-36-8
4-Phenylbenzaldehyde

: 70008-11-6
(2R,3S,4R,5R,6R)-5-Amino-2-azidomethyl-6-methoxy-tetrahydro-pyran-3,4-diol

: (2R,3S,4R,5R,6R)-2-Azidomethyl-5-{[1-biphenyl-4-yl-meth-(E)-ylidene]-amino}-6-methoxy-tetrahydro-pyran-3,4-diol

Guidance literature:: With N-ethyl-N,N-diisopropylamine; In methanol; at 20 ℃; for 2h;
DOI:10.1021/ja045147v

Reference yield:

: 70008-11-6
(2R,3S,4R,5R,6R)-5-Amino-2-azidomethyl-6-methoxy-tetrahydro-pyran-3,4-diol

: (2R,3S,4R,5R,6R)-2-Azidomethyl-5-[(biphenyl-4-ylmethyl)-amino]-6-methoxy-tetrahydro-pyran-3,4-diol

Guidance literature:: Multi-step reaction with 2 steps

1: DIEA / methanol / 2 h / 20 °C

2: 119 mg / NaBH₃CN; AcOH / methanol / 0.5 h

With sodium cyanoborohydride; acetic acid; N-ethyl-N,N-diisopropylamine; In methanol;
DOI:10.1021/ja045147v