benzyl (1-(diphenoxyphosphoryl)-3-(methylthio)propyl)carbamate

Base Information

• Chemical Name: benzyl (1-(diphenoxyphosphoryl)-3-(methylthio)propyl)carbamate
• CAS No.: 174298-10-3
• Molecular Formula: C₂₄H₂₆NO₅PS
• Molecular Weight: 471.514
• Mol file: 174298-10-3.mol

Synonyms:benzyl (1-(diphenoxyphosphoryl)-3-(methylthio)propyl)carbamate

Chemical Property of benzyl (1-(diphenoxyphosphoryl)-3-(methylthio)propyl)carbamate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of benzyl (1-(diphenoxyphosphoryl)-3-(methylthio)propyl)carbamate

There total 1 articles about benzyl (1-(diphenoxyphosphoryl)-3-(methylthio)propyl)carbamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

triphenyl phosphite (101-02-0) + 3-(methylsulfenyl)propanal (3268-49-3) + O-benzyl carbamate (621-84-1) → benzyl (1-(diphenoxyphosphoryl)-3-(methylthio)propyl)carbamate (174298-10-3)

Guidance literature:

DOI:10.1016/j.tetlet.2006.04.058

Reference yield:

benzyl (1-(diphenoxyphosphoryl)-3-(methylthio)propyl)carbamate (174298-10-3) → (1-amino-3-methylsulfanyl-propyl)-phosphonic acid diphenyl ester; hydrobromide

Guidance literature:

With hydrogen bromide; In water; acetic acid;

DOI:10.1016/j.tetlet.2006.04.058

Reference yield:

benzyl (1-(diphenoxyphosphoryl)-3-(methylthio)propyl)carbamate (174298-10-3) → (1-formylamino-3-methylsulfanyl-propyl)-phosphonic acid diphenyl ester (901773-75-9)

Guidance literature:

Multi-step reaction with 2 steps

1: HBr / acetic acid; H₂O

2: 90 percent / Et₃N / CH₂Cl₂ / 0.5 h / 20 °C

With hydrogen bromide; triethylamine; In dichloromethane; water; acetic acid;

DOI:10.1016/j.tetlet.2006.04.058

upstream raw materials:

triphenyl phosphite

3-(methylsulfenyl)propanal

O-benzyl carbamate

Downstream raw materials:

(1-formylamino-3-methylsulfanyl-propyl)-phosphonic acid diphenyl ester