hexacarbonyl-μ-{η⁴-2,2-diphenyl-1,6-dioxaspiro[4.7]dodec-11-yne}dicobalt

Base Information

Chemical Name:hexacarbonyl-μ-{η⁴-2,2-diphenyl-1,6-dioxaspiro[4.7]dodec-11-yne}dicobalt
CAS No.:1449327-62-1
Molecular Formula:C₂₈H₂₂Co₂O₈
Molecular Weight:604.464
Hs Code.:

hexacarbonyl-μ-{η<sup>4</sup>-2,2-diphenyl-1,6-dioxaspiro[4.7]dodec-11-yne}dicobalt

Synonyms:hexacarbonyl-μ-{η⁴-2,2-diphenyl-1,6-dioxaspiro[4.7]dodec-11-yne}dicobalt

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of hexacarbonyl-μ-{η⁴-2,2-diphenyl-1,6-dioxaspiro[4.7]dodec-11-yne}dicobalt

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Technology Process of hexacarbonyl-μ-{η⁴-2,2-diphenyl-1,6-dioxaspiro[4.7]dodec-11-yne}dicobalt

There total 6 articles about hexacarbonyl-μ-{η⁴-2,2-diphenyl-1,6-dioxaspiro[4.7]dodec-11-yne}dicobalt which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: C₂₈H₂₂Co₂O₈

: 1449327-62-1
hexacarbonyl-μ-{η⁴-2,2-diphenyl-1,6-dioxaspiro[4.7]dodec-11-yne}dicobalt

Guidance literature:: With boron trifluoride diethyl etherate; In toluene; at -78 - -20 ℃;
DOI:10.1016/j.tet.2013.05.056

Reference yield:

: 59591-01-4
2,2-diphenylcyclopropanecarbaldehyde

: 1449327-62-1
hexacarbonyl-μ-{η⁴-2,2-diphenyl-1,6-dioxaspiro[4.7]dodec-11-yne}dicobalt

Guidance literature:: Multi-step reaction with 5 steps

1: n-butyllithium / tetrahydrofuran / -78 °C

2: acetic acid; tetrabutyl ammonium fluoride / tetrahydrofuran / 20 °C

3: manganese(IV) oxide / dichloromethane

4: dichloromethane / 20 °C

5: boron trifluoride diethyl etherate / toluene / -78 - -20 °C

With manganese(IV) oxide; n-butyllithium; boron trifluoride diethyl etherate; tetrabutyl ammonium fluoride; acetic acid; In tetrahydrofuran; dichloromethane; toluene;
DOI:10.1016/j.tet.2013.05.056

Reference yield:

: 37555-48-9
2,2-diphenylcyclopropylmethanol

: 1449327-62-1
hexacarbonyl-μ-{η⁴-2,2-diphenyl-1,6-dioxaspiro[4.7]dodec-11-yne}dicobalt

Guidance literature:: Multi-step reaction with 6 steps

1: pyridinium chlorochromate / dichloromethane / 20 °C

2: n-butyllithium / tetrahydrofuran / -78 °C

3: acetic acid; tetrabutyl ammonium fluoride / tetrahydrofuran / 20 °C

4: manganese(IV) oxide / dichloromethane

5: dichloromethane / 20 °C

6: boron trifluoride diethyl etherate / toluene / -78 - -20 °C

With manganese(IV) oxide; n-butyllithium; boron trifluoride diethyl etherate; tetrabutyl ammonium fluoride; acetic acid; pyridinium chlorochromate; In tetrahydrofuran; dichloromethane; toluene;
DOI:10.1016/j.tet.2013.05.056