4-(2-(4-bromophenyl)-1H-phenanthro[9,10-d]Imidazol-1-yl)benzonitrile

Base Information

• Chemical Name: 4-(2-(4-bromophenyl)-1H-phenanthro[9,10-d]Imidazol-1-yl)benzonitrile
• CAS No.: 1619222-82-0
• Molecular Formula: C₂₈H₁₆BrN₃
• Molecular Weight: 474.359
• Mol file: 1619222-82-0.mol

Synonyms:4-(2-(4-bromophenyl)-1H-phenanthro[9,10-d]Imidazol-1-yl)benzonitrile

Chemical Property of 4-(2-(4-bromophenyl)-1H-phenanthro[9,10-d]Imidazol-1-yl)benzonitrile

Chemical Property:

Purity/Quality:

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Technology Process of 4-(2-(4-bromophenyl)-1H-phenanthro[9,10-d]Imidazol-1-yl)benzonitrile

There total 1 articles about 4-(2-(4-bromophenyl)-1H-phenanthro[9,10-d]Imidazol-1-yl)benzonitrile which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

4-bromo-benzaldehyde (1122-91-4) + 9,10-phenanthrenequinone (84-11-7) + 4-Aminobenzonitrile (873-74-5) → 4-(2-(4-bromophenyl)-1H-phenanthro[9,10-d]Imidazol-1-yl)benzonitrile (1619222-82-0)

Guidance literature:

With ammonium acetate; In acetic acid; at 120 ℃; for 12h; Inert atmosphere; Schlenk technique;

DOI:10.1002/chem.202005214

Reference yield: 96.0%

4-(carbazol-9-yl)phenylboronic acid (419536-33-7) + 4-(2-(4-bromophenyl)-1H-phenanthro[9,10-d]Imidazol-1-yl)benzonitrile (1619222-82-0) → 4-(2-(4'-(9H-carbazol-9-yl)-[1,1'-biphenyl]-4-yl)-1Hphenanthro[9,10-d]imidazol-1-yl)benzonitrile

Guidance literature:

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate; In ethanol; water; toluene; at 90 ℃; for 24h; Inert atmosphere;

DOI:10.1039/c7tc04089j

Reference yield: 85.8%

4-(2-(4-bromophenyl)-1H-phenanthro[9,10-d]Imidazol-1-yl)benzonitrile (1619222-82-0) + 4-(diphenylamino)phenyl boronic acid (201802-67-7) → 4-[2-(4′-diphenylaminobiphenyl-4-yl)phenanthro[9,10-d]imidazol-1-yl]benzonitrile

Guidance literature:

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate; In 1,4-dioxane; at 90 ℃; for 12h; Inert atmosphere; Schlenk technique;

DOI:10.1002/chem.202005214

upstream raw materials:

4-bromo-benzaldehyde

9,10-phenanthrenequinone

4-Aminobenzonitrile

Downstream raw materials:

C₅₄H₃₅N₃