ethyl (E)-3-O-methyl-5,6-dideoxy-1,2-O-isopropylidene-6-C-phenylmethyl-α-D-xylo-hept-5-enofuranuronate

Base Information

• Chemical Name: ethyl (E)-3-O-methyl-5,6-dideoxy-1,2-O-isopropylidene-6-C-phenylmethyl-α-D-xylo-hept-5-enofuranuronate
• CAS No.: 1310802-52-8
• Molecular Formula: C₂₀H₂₆O₆
• Molecular Weight: 362.423
• Mol file: 1310802-52-8.mol

Synonyms:ethyl (E)-3-O-methyl-5,6-dideoxy-1,2-O-isopropylidene-6-C-phenylmethyl-α-D-xylo-hept-5-enofuranuronate

Chemical Property of ethyl (E)-3-O-methyl-5,6-dideoxy-1,2-O-isopropylidene-6-C-phenylmethyl-α-D-xylo-hept-5-enofuranuronate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of ethyl (E)-3-O-methyl-5,6-dideoxy-1,2-O-isopropylidene-6-C-phenylmethyl-α-D-xylo-hept-5-enofuranuronate

There total 1 articles about ethyl (E)-3-O-methyl-5,6-dideoxy-1,2-O-isopropylidene-6-C-phenylmethyl-α-D-xylo-hept-5-enofuranuronate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

ethyl 2,2-dichloro-3-phenylpropionate (19754-40-6) + 1,2-O-isopropylidene-3-O-methyl-α-D-xylo-pentodialdo-1,4-furanose (18968-51-9,43138-66-5,63522-21-4,816444-37-8) → ethyl (E)-3-O-methyl-5,6-dideoxy-1,2-O-isopropylidene-6-C-phenylmethyl-α-D-xylo-hept-5-enofuranuronate (1310802-52-8)

Guidance literature:

With chromium dichloride; In tetrahydrofuran; at 75 ℃; for 3h; optical yield given as %de; stereoselective reaction; Inert atmosphere;

DOI:10.1021/jo200548g

upstream raw materials:

ethyl 2,2-dichloro-3-phenylpropionate

1,2-O-isopropylidene-3-O-methyl-α-D-xylo-pentodialdo-1,4-furanose