triethyl({(1R,2R,3Z)-2-isopropyl-3-methyl-4-[(S)-N-methyl-S-phenylsulfonimidoyl]-1-phenylbut-3-enyl}oxy)silane

Base Information

• Chemical Name: triethyl({(1R,2R,3Z)-2-isopropyl-3-methyl-4-[(S)-N-methyl-S-phenylsulfonimidoyl]-1-phenylbut-3-enyl}oxy)silane
• CAS No.: 691872-61-4
• Molecular Formula: C₂₇H₄₁NO₂SSi
• Molecular Weight: 471.78
• Mol file: 691872-61-4.mol

Synonyms:triethyl({(1R,2R,3Z)-2-isopropyl-3-methyl-4-[(S)-N-methyl-S-phenylsulfonimidoyl]-1-phenylbut-3-enyl}oxy)silane

Chemical Property of triethyl({(1R,2R,3Z)-2-isopropyl-3-methyl-4-[(S)-N-methyl-S-phenylsulfonimidoyl]-1-phenylbut-3-enyl}oxy)silane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of triethyl({(1R,2R,3Z)-2-isopropyl-3-methyl-4-[(S)-N-methyl-S-phenylsulfonimidoyl]-1-phenylbut-3-enyl}oxy)silane

There total 1 articles about triethyl({(1R,2R,3Z)-2-isopropyl-3-methyl-4-[(S)-N-methyl-S-phenylsulfonimidoyl]-1-phenylbut-3-enyl}oxy)silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C14H21NOS → triethyl({(1R,2R,3Z)-2-isopropyl-3-methyl-4-[(S)-N-methyl-S-phenylsulfonimidoyl]-1-phenylbut-3-enyl}oxy)silane (691872-61-4)

Guidance literature:

Multi-step reaction with 2 steps

1.1: BuLi / tetrahydrofuran; hexane / 1 h / -78 °C

1.2: ClTi(OiPr)3 / tetrahydrofuran; hexane / 2.5 h / -78 - 0 °C

1.3: tetrahydrofuran; hexane / 2 h / -78 °C

2.1: 96 percent / imidazole / dimethylformamide / 20 h / 20 °C

With 1H-imidazole; n-butyllithium; In tetrahydrofuran; hexane; N,N-dimethyl-formamide;

DOI:10.1021/ja030501v

Reference yield:

triethyl({(1R,2R,3Z)-2-isopropyl-3-methyl-4-[(S)-N-methyl-S-phenylsulfonimidoyl]-1-phenylbut-3-enyl}oxy)silane (691872-61-4) → triethyl-[(4R,5R)-4-isopropyl-3-methyl-5-phenyl-4,5-dihydrofuran-2-yl]silane

Guidance literature:

Multi-step reaction with 2 steps

1: CH₂Cl₂ / 1 h / 20 °C

2: LiN(H)t-Bu / tetrahydrofuran / 15 h / 20 °C

With lithium tert-butylamide; In tetrahydrofuran; dichloromethane;

DOI:10.1021/ja030501v

Reference yield:

trimethoxonium tetrafluoroborate (420-37-1) + triethyl({(1R,2R,3Z)-2-isopropyl-3-methyl-4-[(S)-N-methyl-S-phenylsulfonimidoyl]-1-phenylbut-3-enyl}oxy)silane (691872-61-4) → C28H44NO2SSi(1+)*BF4(1-)

Guidance literature:

In dichloromethane; at 20 ℃; for 1h;

DOI:10.1021/ja030501v