di-i-propyl 2-(4-(trifluoromethyl)phenyl)allylphosphonate

Base Information

• Chemical Name: di-i-propyl 2-(4-(trifluoromethyl)phenyl)allylphosphonate
• CAS No.: 1198157-69-5
• Molecular Formula: C₁₆H₂₂F₃O₃P
• Molecular Weight: 350.318
• Mol file: 1198157-69-5.mol

Synonyms:di-i-propyl 2-(4-(trifluoromethyl)phenyl)allylphosphonate

Chemical Property of di-i-propyl 2-(4-(trifluoromethyl)phenyl)allylphosphonate

Chemical Property:

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Technology Process of di-i-propyl 2-(4-(trifluoromethyl)phenyl)allylphosphonate

There total 1 articles about di-i-propyl 2-(4-(trifluoromethyl)phenyl)allylphosphonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

triisopropyl phosphite (116-17-6) + 1-(3-bromoprop-1-en-2-yl)-4-(trifluoromethyl)benzene (1234835-64-3) → di-i-propyl 2-(4-(trifluoromethyl)phenyl)allylphosphonate (1198157-69-5)

Guidance literature:

Inert atmosphere; Reflux;

DOI:10.1021/jo901619c

Reference yield:

di-i-propyl 2-(4-(trifluoromethyl)phenyl)allylphosphonate (1198157-69-5) → di-i-propyl 2-(4-trifluoromethylphenyl)propylphosphonate

Guidance literature:

With bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate; C₃₉H₃₂FeNO₂P; hydrogen; In dichloromethane; at 20 ℃; for 24h; under 7600.51 Torr; enantioselective reaction;

DOI:10.1021/jo901619c

upstream raw materials:

triisopropyl phosphite

1-(3-bromoprop-1-en-2-yl)-4-(trifluoromethyl)benzene