Technology Process of C26H39NO2S2Si
There total 5 articles about C26H39NO2S2Si which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
2,6-dimethylpyridine;
In
dichloromethane;
at 0 ℃;
for 0.5h;
Inert atmosphere;
DOI:10.1021/jo400929m
- Guidance literature:
-
Multi-step reaction with 5 steps
1.1: zirconocene dichloride / 1,2-dichloro-ethane / 24 h / 0 - 20 °C / Inert atmosphere
1.2: 0.5 h / 0 °C / Inert atmosphere
2.1: tetrakis(triphenylphosphine) palladium(0) / toluene / 3 h / 0 - 20 °C / Inert atmosphere
3.1: oxalyl dichloride; dimethyl sulfoxide; triethylamine / dichloromethane / 2 h / -78 - 0 °C / Inert atmosphere
4.1: titanium tetrachloride; N-ethyl-N,N-diisopropylamine / dichloromethane / 1 h / -40 °C / Inert atmosphere
4.2: 0.33 h / -78 - -40 °C / Inert atmosphere
5.1: 2,6-dimethylpyridine / dichloromethane / 0.5 h / 0 °C / Inert atmosphere
With
2,6-dimethylpyridine; tetrakis(triphenylphosphine) palladium(0); zirconocene dichloride; oxalyl dichloride; titanium tetrachloride; dimethyl sulfoxide; triethylamine; N-ethyl-N,N-diisopropylamine;
In
dichloromethane; 1,2-dichloro-ethane; toluene;
1.1: |Negishi Coupling / 2.1: |Kumada Cross-Coupling / 3.1: |Swern Oxidation / 4.2: |Aldol Addition;
DOI:10.1021/jo400929m
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: oxalyl dichloride; dimethyl sulfoxide; triethylamine / dichloromethane / 2 h / -78 - 0 °C / Inert atmosphere
2.1: titanium tetrachloride; N-ethyl-N,N-diisopropylamine / dichloromethane / 1 h / -40 °C / Inert atmosphere
2.2: 0.33 h / -78 - -40 °C / Inert atmosphere
3.1: 2,6-dimethylpyridine / dichloromethane / 0.5 h / 0 °C / Inert atmosphere
With
2,6-dimethylpyridine; oxalyl dichloride; titanium tetrachloride; dimethyl sulfoxide; triethylamine; N-ethyl-N,N-diisopropylamine;
In
dichloromethane;
1.1: |Swern Oxidation / 2.2: |Aldol Addition;
DOI:10.1021/jo400929m