1-[(E)-(S)-3-Allyloxy-3-((1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl)-1-methyl-propenyl]-4-methyl-benzene

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Chemical Name:1-[(E)-(S)-3-Allyloxy-3-((1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl)-1-methyl-propenyl]-4-methyl-benzene
CAS No.:795278-40-9
Molecular Formula:C₂₄H₃₆O
Molecular Weight:340.549
Hs Code.:

Synonyms:1-[(E)-(S)-3-Allyloxy-3-((1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl)-1-methyl-propenyl]-4-methyl-benzene

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Chemical Property of 1-[(E)-(S)-3-Allyloxy-3-((1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl)-1-methyl-propenyl]-4-methyl-benzene

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Technology Process of 1-[(E)-(S)-3-Allyloxy-3-((1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl)-1-methyl-propenyl]-4-methyl-benzene

There total 1 articles about 1-[(E)-(S)-3-Allyloxy-3-((1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl)-1-methyl-propenyl]-4-methyl-benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

: 106-95-6
allyl bromide

: 795280-30-7
(E)-(S)-1-((1R,2S,5R)-2-Isopropyl-5-methyl-cyclohexyl)-3-p-tolyl-but-2-en-1-ol

: 795278-40-9
1-[(E)-(S)-3-Allyloxy-3-((1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl)-1-methyl-propenyl]-4-methyl-benzene

Guidance literature:: (E)-(S)-1-((1R,2S,5R)-2-Isopropyl-5-methyl-cyclohexyl)-3-p-tolyl-but-2-en-1-ol; With sodium hydride; sodium iodide; In 1,2-dimethoxyethane;

allyl bromide; In 1,2-dimethoxyethane; at 20 ℃; for 48h;
DOI:10.1021/ja046084j

Reference yield:

: 795278-40-9
1-[(E)-(S)-3-Allyloxy-3-((1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl)-1-methyl-propenyl]-4-methyl-benzene

: (E)-(S)-6-((1S,2S,5R)-2-Isopropyl-5-methyl-cyclohexyl)-4-methyl-4-p-tolyl-hexa-1,5-dien-3-one

Guidance literature:: Multi-step reaction with 2 steps

1: 80 percent / n-BuLi / tetrahydrofuran; hexane / -85 - 20 °C

2: 77 percent / Dess-Martin periodinane / CH₂Cl₂ / 0.33 h / 20 °C

With n-butyllithium; Dess-Martin periodane; In tetrahydrofuran; hexane; dichloromethane; 1: <2,3>-Wittig rearrangement;
DOI:10.1021/ja046084j