Technology Process of C30H32O3Si
There total 1 articles about C30H32O3Si which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
Multi-step reaction with 2 steps
1: (5S,8R,9R)-2,2-dimethyl-10-oxo-1,3,6-trioxaspiro[4.5]decane-8,9-diyl diacetate; oxone; tetra(n-butyl)ammonium hydrogensulfate; potassium carbonate / Dimethoxymethane; acetonitrile / 26 h / 0 °C / pH 6 / aq. buffer
2: tetrabutyl ammonium fluoride / tetrahydrofuran / 4 h / 0 - 20 °C
With
(5S,8R,9R)-2,2-dimethyl-10-oxo-1,3,6-trioxaspiro[4.5]decane-8,9-diyl diacetate; oxone; tetrabutyl ammonium fluoride; tetra(n-butyl)ammonium hydrogensulfate; potassium carbonate;
In
tetrahydrofuran; Dimethoxymethane; acetonitrile;
1: Shi type epoxidation;
DOI:10.1002/adsc.201000505
- Guidance literature:
-
Multi-step reaction with 2 steps
1: (5S,8R,9R)-2,2-dimethyl-10-oxo-1,3,6-trioxaspiro[4.5]decane-8,9-diyl diacetate; oxone; tetra(n-butyl)ammonium hydrogensulfate; potassium carbonate / Dimethoxymethane; acetonitrile / 26 h / 0 °C / pH 6 / aq. buffer
2: potassium fluoride; 18-crown-6 ether; trifluoroacetic acid / tetrahydrofuran / 17 h / 20 °C
With
(5S,8R,9R)-2,2-dimethyl-10-oxo-1,3,6-trioxaspiro[4.5]decane-8,9-diyl diacetate; potassium fluoride; oxone; 18-crown-6 ether; tetra(n-butyl)ammonium hydrogensulfate; potassium carbonate; trifluoroacetic acid;
In
tetrahydrofuran; Dimethoxymethane; acetonitrile;
1: Shi type epoxidation;
DOI:10.1002/adsc.201000505