1,3-bis(2,6-diisopropylphenyl)imidazolinium-2-dithiocarboxylate

Base Information

• Chemical Name: 1,3-bis(2,6-diisopropylphenyl)imidazolinium-2-dithiocarboxylate
• CAS No.: 917604-51-4
• Molecular Formula: C₂₈H₃₈N₂S₂
• Molecular Weight: 466.755
• Mol file: 917604-51-4.mol

Synonyms:1,3-bis(2,6-diisopropylphenyl)imidazolinium-2-dithiocarboxylate

Chemical Property of 1,3-bis(2,6-diisopropylphenyl)imidazolinium-2-dithiocarboxylate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1,3-bis(2,6-diisopropylphenyl)imidazolinium-2-dithiocarboxylate

There total 1 articles about 1,3-bis(2,6-diisopropylphenyl)imidazolinium-2-dithiocarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

carbon disulfide (75-15-0,12122-00-8) + 1,3-bis[(2,6-diisopropyl)phenyl]imidazolinium chloride (258278-25-0) → 1,3-bis(2,6-diisopropylphenyl)imidazolinium-2-dithiocarboxylate (917604-51-4)

Guidance literature:

With potassium carbonate; In tetrahydrofuran; at 80 ℃; for 24h; Glovebox;

DOI:10.1007/s11164-014-1634-5

Reference yield: 99.0%

[ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2 (52462-29-0) + 1,3-bis(2,6-diisopropylphenyl)imidazolinium-2-dithiocarboxylate (917604-51-4) → [RuCl(η6-p-cymene)(k2-S,S'-S2C·SIdip)]Cl

Guidance literature:

In dichloromethane; at 20 ℃; for 0.166667h; Inert atmosphere; Schlenk technique;

DOI:10.1021/acs.inorgchem.1c02648

Reference yield: 98.0%

[ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2 (52462-29-0) + 1,3-bis(2,6-diisopropylphenyl)imidazolinium-2-dithiocarboxylate (917604-51-4) → [RuCl(η6-p-cymene)(k2-S,S'-S2C·SIdip)][RuCl(η6-p-cymene)]

Guidance literature:

With 1,3-bis(2,4,6-trimethylphenyl)imidazolium-2-dithiocarboxylate; at 20 ℃; for 0.166667h; Inert atmosphere; Schlenk technique;

DOI:10.1021/acs.inorgchem.1c02648

upstream raw materials:

carbon disulfide

1,3-bis[(2,6-diisopropyl)phenyl]imidazolinium chloride

Downstream raw materials:

[RuCl(p-cymene)(S₂CC₃H₄N₂(C₆H₃-i-Pr₂)2)]PF₆