(1S,3S,4S,5R,6R,7R)-6,7-Diacetoxy-1-((4R,5R)-4-acetoxy-5-methyl-6-phenyl-hexyl)-4-hydroxy-4-vinyl-2,8-dioxa-bicyclo[3.2.1]octane-3,5-dicarboxylic acid di-tert-butyl ester

Base Information

Chemical Name:(1S,3S,4S,5R,6R,7R)-6,7-Diacetoxy-1-((4R,5R)-4-acetoxy-5-methyl-6-phenyl-hexyl)-4-hydroxy-4-vinyl-2,8-dioxa-bicyclo[3.2.1]octane-3,5-dicarboxylic acid di-tert-butyl ester
CAS No.:164215-51-4
Molecular Formula:C₃₇H₅₂O₁₃
Molecular Weight:704.812
Hs Code.:

(1S,3S,4S,5R,6R,7R)-6,7-Diacetoxy-1-((4R,5R)-4-acetoxy-5-methyl-6-phenyl-hexyl)-4-hydroxy-4-vinyl-2,8-dioxa-bicyclo[3.2.1]octane-3,5-dicarboxylic acid di-tert-butyl ester

Synonyms:(1S,3S,4S,5R,6R,7R)-6,7-Diacetoxy-1-((4R,5R)-4-acetoxy-5-methyl-6-phenyl-hexyl)-4-hydroxy-4-vinyl-2,8-dioxa-bicyclo[3.2.1]octane-3,5-dicarboxylic acid di-tert-butyl ester

Suppliers and Price of (1S,3S,4S,5R,6R,7R)-6,7-Diacetoxy-1-((4R,5R)-4-acetoxy-5-methyl-6-phenyl-hexyl)-4-hydroxy-4-vinyl-2,8-dioxa-bicyclo[3.2.1]octane-3,5-dicarboxylic acid di-tert-butyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (1S,3S,4S,5R,6R,7R)-6,7-Diacetoxy-1-((4R,5R)-4-acetoxy-5-methyl-6-phenyl-hexyl)-4-hydroxy-4-vinyl-2,8-dioxa-bicyclo[3.2.1]octane-3,5-dicarboxylic acid di-tert-butyl ester

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (1S,3S,4S,5R,6R,7R)-6,7-Diacetoxy-1-((4R,5R)-4-acetoxy-5-methyl-6-phenyl-hexyl)-4-hydroxy-4-vinyl-2,8-dioxa-bicyclo[3.2.1]octane-3,5-dicarboxylic acid di-tert-butyl ester

There total 26 articles about (1S,3S,4S,5R,6R,7R)-6,7-Diacetoxy-1-((4R,5R)-4-acetoxy-5-methyl-6-phenyl-hexyl)-4-hydroxy-4-vinyl-2,8-dioxa-bicyclo[3.2.1]octane-3,5-dicarboxylic acid di-tert-butyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 164215-43-4
(1S,3R,4S,5R,6R,7R)-3,5-Bis-(tert-butyl-dimethyl-silanyloxymethyl)-4-ethynyl-1-((4R,5R)-4-hydroxy-5-methyl-6-phenyl-hexyl)-2,8-dioxa-bicyclo[3.2.1]octane-4,6,7-triol

: 164215-51-4
(1S,3S,4S,5R,6R,7R)-6,7-Diacetoxy-1-((4R,5R)-4-acetoxy-5-methyl-6-phenyl-hexyl)-4-hydroxy-4-vinyl-2,8-dioxa-bicyclo[3.2.1]octane-3,5-dicarboxylic acid di-tert-butyl ester

Guidance literature:: Multi-step reaction with 10 steps

1: 94 percent / 4-DMAP / CH₂Cl₂ / 12 h

2: 90 percent / Cl₂CHCO₂H / methanol / 7 h

3: H₂ / 5percent Pd/C / pyridine / 2 h / 760 Torr

4: 94 percent / Dess-Martin periodinane / CH₂Cl₂ / 2 h / 23 °C

5: aq. NaClO₂ / 2-methyl-propan-2-ol; various solvent(s) / 3 h / 10 °C

6: CH₂Cl₂ / 22 h

7: 90 percent / HF*pyridine / tetrahydrofuran

8: 84 percent / Dess-Martin periodinane, pyridine / CH₂Cl₂ / 0.58 h / 23 °C

9: aq. NaClO₂ / 2-methyl-propan-2-ol; various solvent(s) / 3 h / 10 °C

10: CH₂Cl₂ / 22 h

With pyridine; dichloro-acetic acid; dmap; sodium chlorite; hydrogen; Dess-Martin periodane; pyridine hydrogenfluoride; palladium on activated charcoal; In tetrahydrofuran; pyridine; methanol; dichloromethane; tert-butyl alcohol;
DOI:10.1021/ja00136a008

Reference yield:

: 164215-45-6
Acetic acid (1S,3R,4S,5R,6R,7R)-7-acetoxy-1-((4R,5R)-4-acetoxy-5-methyl-6-phenyl-hexyl)-5-(tert-butyl-dimethyl-silanyloxymethyl)-4-ethynyl-4-hydroxy-3-hydroxymethyl-2,8-dioxa-bicyclo[3.2.1]oct-6-yl ester

: 164215-51-4
(1S,3S,4S,5R,6R,7R)-6,7-Diacetoxy-1-((4R,5R)-4-acetoxy-5-methyl-6-phenyl-hexyl)-4-hydroxy-4-vinyl-2,8-dioxa-bicyclo[3.2.1]octane-3,5-dicarboxylic acid di-tert-butyl ester

Guidance literature:: Multi-step reaction with 8 steps

1: H₂ / 5percent Pd/C / pyridine / 2 h / 760 Torr

2: 94 percent / Dess-Martin periodinane / CH₂Cl₂ / 2 h / 23 °C

3: aq. NaClO₂ / 2-methyl-propan-2-ol; various solvent(s) / 3 h / 10 °C

4: CH₂Cl₂ / 22 h

5: 90 percent / HF*pyridine / tetrahydrofuran

6: 84 percent / Dess-Martin periodinane, pyridine / CH₂Cl₂ / 0.58 h / 23 °C

7: aq. NaClO₂ / 2-methyl-propan-2-ol; various solvent(s) / 3 h / 10 °C

8: CH₂Cl₂ / 22 h

With pyridine; sodium chlorite; hydrogen; Dess-Martin periodane; pyridine hydrogenfluoride; palladium on activated charcoal; In tetrahydrofuran; pyridine; dichloromethane; tert-butyl alcohol;
DOI:10.1021/ja00136a008

Reference yield:

: 164215-44-5
Acetic acid (1S,3R,4S,5R,6R,7R)-7-acetoxy-1-((4R,5R)-4-acetoxy-5-methyl-6-phenyl-hexyl)-3,5-bis-(tert-butyl-dimethyl-silanyloxymethyl)-4-ethynyl-4-hydroxy-2,8-dioxa-bicyclo[3.2.1]oct-6-yl ester

: 164215-51-4
(1S,3S,4S,5R,6R,7R)-6,7-Diacetoxy-1-((4R,5R)-4-acetoxy-5-methyl-6-phenyl-hexyl)-4-hydroxy-4-vinyl-2,8-dioxa-bicyclo[3.2.1]octane-3,5-dicarboxylic acid di-tert-butyl ester

Guidance literature:: Multi-step reaction with 9 steps

1: 90 percent / Cl₂CHCO₂H / methanol / 7 h

2: H₂ / 5percent Pd/C / pyridine / 2 h / 760 Torr

3: 94 percent / Dess-Martin periodinane / CH₂Cl₂ / 2 h / 23 °C

4: aq. NaClO₂ / 2-methyl-propan-2-ol; various solvent(s) / 3 h / 10 °C

5: CH₂Cl₂ / 22 h

6: 90 percent / HF*pyridine / tetrahydrofuran

7: 84 percent / Dess-Martin periodinane, pyridine / CH₂Cl₂ / 0.58 h / 23 °C

8: aq. NaClO₂ / 2-methyl-propan-2-ol; various solvent(s) / 3 h / 10 °C

9: CH₂Cl₂ / 22 h

With pyridine; dichloro-acetic acid; sodium chlorite; hydrogen; Dess-Martin periodane; pyridine hydrogenfluoride; palladium on activated charcoal; In tetrahydrofuran; pyridine; methanol; dichloromethane; tert-butyl alcohol;
DOI:10.1021/ja00136a008