(R,R)-(bicyclo[2.2.1]hepta-2,5-diene)[1,2-phenylenebis(methylphenylphosphine)]rhodium(I) hexafluorophosphate diacetone

Base Information

Chemical Name:(R*,R*)-(bicyclo[2.2.1]hepta-2,5-diene)[1,2-phenylenebis(methylphenylphosphine)]rhodium(I) hexafluorophosphate diacetone
CAS No.:101052-77-1
Molecular Formula:2C₃H₆O*C₂₇H₂₈P₂Rh*F₆P
Molecular Weight:778.497
Hs Code.:

Synonyms:(R*,R*)-(bicyclo[2.2.1]hepta-2,5-diene)[1,2-phenylenebis(methylphenylphosphine)]rhodium(I) hexafluorophosphate diacetone

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Chemical Property of (R*,R*)-(bicyclo[2.2.1]hepta-2,5-diene)[1,2-phenylenebis(methylphenylphosphine)]rhodium(I) hexafluorophosphate diacetone

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Technology Process of (R*,R*)-(bicyclo[2.2.1]hepta-2,5-diene)[1,2-phenylenebis(methylphenylphosphine)]rhodium(I) hexafluorophosphate diacetone

There total 1 articles about (R*,R*)-(bicyclo[2.2.1]hepta-2,5-diene)[1,2-phenylenebis(methylphenylphosphine)]rhodium(I) hexafluorophosphate diacetone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: ammonium hexafluorophosphate

: 12257-42-0
[(norbornadiene)rhodium(I)chloride]2

: 72091-01-1,72091-02-2,72150-36-8,72150-63-1,77410-05-0
(RS)-o-phenylenebis(methylphenylphosphine)

: 101052-77-1
(R*,R*)-(bicyclo[2.2.1]hepta-2,5-diene)[1,2-phenylenebis(methylphenylphosphine)]rhodium(I) hexafluorophosphate diacetone

Guidance literature:: With silver nitrate; acetone; In methanol; water; byproducts: AgCl; stirring of Rh complex and AgNO3 in MeOH under Ar for 30 min, cooling to -78°C, addn. of ligand, after 1 h warming to room temp., filtn., of AgCl, treating with aq. NH4PF6; filtn. washing with water, drying, recrystn. from acetone and Et2O, elem. anal.;
DOI:10.1021/om00136a029

Reference yield: 90.0%

: 101052-77-1
(R*,R*)-(bicyclo[2.2.1]hepta-2,5-diene)[1,2-phenylenebis(methylphenylphosphine)]rhodium(I) hexafluorophosphate diacetone

: 101052-79-3
Rh₂(C₆H₄(PCH₃C₆H₅)2)2⁽²⁺⁾*2PF₆^(1-)*0.5CH₂Cl₂=Rh₂(C₆H₄(PCH₃C₆H₅)2)2(PF₆)2*0.5CH₂Cl₂

Guidance literature:: With hydrogen; In dichloromethane; a soln. of Rh complex was stirred under 1 atm H2 for 15 h; filtn., recrystallization from hot CH2Cl2, elem. anal.;
DOI:10.1021/om00136a029