(S)-isopropyl 3-(tert-butyldimethylsilyloxy)-5-phenylpentanoate

Base Information

• Chemical Name: (S)-isopropyl 3-(tert-butyldimethylsilyloxy)-5-phenylpentanoate
• CAS No.: 1174045-07-8
• Molecular Formula: C₂₀H₃₄O₃Si
• Molecular Weight: 350.574
• Mol file: 1174045-07-8.mol

Synonyms:(S)-isopropyl 3-(tert-butyldimethylsilyloxy)-5-phenylpentanoate

Chemical Property of (S)-isopropyl 3-(tert-butyldimethylsilyloxy)-5-phenylpentanoate

Chemical Property:

Purity/Quality:

Safty Information:

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Technology Process of (S)-isopropyl 3-(tert-butyldimethylsilyloxy)-5-phenylpentanoate

There total 1 articles about (S)-isopropyl 3-(tert-butyldimethylsilyloxy)-5-phenylpentanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

3-phenyl-propionaldehyde (104-53-0) + tert-butyl((1-methoxy-2-methylprop-1-en-1-yl)oxy)dimethylsilane (124193-25-5) → (R)-isopropyl 3-(tert-butyldimethylsilyloxy)-5-phenylpentanoate + (S)-isopropyl 3-(tert-butyldimethylsilyloxy)-5-phenylpentanoate (1174045-07-8)

Guidance literature:

With 3,3’-bis[3,5-bis(perfluoropropan-2-yl)phenyl]-1,1’-binaphthalene-2,2’-sulfonimide; In diethyl ether; at 20 ℃; for 49h; optical yield given as %ee; enantioselective reaction;

DOI:10.1002/anie.200901768

upstream raw materials:

3-phenyl-propionaldehyde

tert-butyl((1-methoxy-2-methylprop-1-en-1-yl)oxy)dimethylsilane