1-[(E)-2-Benzenesulfonyl-3-(toluene-4-sulfonyloxy)-allyl]-2,2-dimethyl-6-oxo-cyclohexanecarboxylic acid methyl ester

Base Information

Chemical Name:1-[(E)-2-Benzenesulfonyl-3-(toluene-4-sulfonyloxy)-allyl]-2,2-dimethyl-6-oxo-cyclohexanecarboxylic acid methyl ester
CAS No.:848779-07-7
Molecular Formula:C₂₆H₃₀O₈S₂
Molecular Weight:534.651
Hs Code.:

Synonyms:1-[(E)-2-Benzenesulfonyl-3-(toluene-4-sulfonyloxy)-allyl]-2,2-dimethyl-6-oxo-cyclohexanecarboxylic acid methyl ester

Suppliers and Price of 1-[(E)-2-Benzenesulfonyl-3-(toluene-4-sulfonyloxy)-allyl]-2,2-dimethyl-6-oxo-cyclohexanecarboxylic acid methyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 1-[(E)-2-Benzenesulfonyl-3-(toluene-4-sulfonyloxy)-allyl]-2,2-dimethyl-6-oxo-cyclohexanecarboxylic acid methyl ester

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 1-[(E)-2-Benzenesulfonyl-3-(toluene-4-sulfonyloxy)-allyl]-2,2-dimethyl-6-oxo-cyclohexanecarboxylic acid methyl ester

There total 5 articles about 1-[(E)-2-Benzenesulfonyl-3-(toluene-4-sulfonyloxy)-allyl]-2,2-dimethyl-6-oxo-cyclohexanecarboxylic acid methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 848778-98-3
1-((E)-3-Acetoxy-2-benzenesulfonyl-allyl)-2,2-dimethyl-6-oxo-cyclohexanecarboxylic acid methyl ester

: 98-59-9
p-toluenesulfonyl chloride

: 848779-07-7
1-[(E)-2-Benzenesulfonyl-3-(toluene-4-sulfonyloxy)-allyl]-2,2-dimethyl-6-oxo-cyclohexanecarboxylic acid methyl ester

Guidance literature:: 1-((E)-3-Acetoxy-2-benzenesulfonyl-allyl)-2,2-dimethyl-6-oxo-cyclohexanecarboxylic acid methyl ester; With potassium tert-butylate; In tetrahydrofuran; at 0 ℃; for 1h;

p-toluenesulfonyl chloride; In tetrahydrofuran;
DOI:10.1016/j.tet.2004.12.044

Reference yield:

: acetic acid 1-acetoxy-3-chloro-2-phenylsulfanyl-propyl ester

: 848779-07-7
1-[(E)-2-Benzenesulfonyl-3-(toluene-4-sulfonyloxy)-allyl]-2,2-dimethyl-6-oxo-cyclohexanecarboxylic acid methyl ester

Guidance literature:: Multi-step reaction with 4 steps

1.1: m-chloroperbenzoic acid / CH₂Cl₂ / 0.33 h

2.1: diisopropylethylamine / CH₂Cl₂ / 2 h / 0 °C

3.1: sodium hydride / tetrahydrofuran / 0.33 h

3.2: 70 percent / tetrahydrofuran / 1 h

4.1: potassium tert-butoxide / tetrahydrofuran / 1 h / 0 °C

4.2: tetrahydrofuran

With potassium tert-butylate; sodium hydride; N-ethyl-N,N-diisopropylamine; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; dichloromethane; 3.2: Michael addition;
DOI:10.1016/j.tet.2004.12.044

Reference yield:

: 848778-96-1
acetic acid 1-acetoxy-2-benzenesulfonyl-allyl ester

: 848779-07-7
1-[(E)-2-Benzenesulfonyl-3-(toluene-4-sulfonyloxy)-allyl]-2,2-dimethyl-6-oxo-cyclohexanecarboxylic acid methyl ester

Guidance literature:: Multi-step reaction with 2 steps

1.1: sodium hydride / tetrahydrofuran / 0.33 h

1.2: 70 percent / tetrahydrofuran / 1 h

2.1: potassium tert-butoxide / tetrahydrofuran / 1 h / 0 °C

2.2: tetrahydrofuran

With potassium tert-butylate; sodium hydride; In tetrahydrofuran; 1.2: Michael addition;
DOI:10.1016/j.tet.2004.12.044