dichlorophenyl(1,1,2-trimethylpropyl)silane

Base Information

• Chemical Name: dichlorophenyl(1,1,2-trimethylpropyl)silane
• CAS No.: 217486-36-7
• Molecular Formula: C₁₂H₁₈Cl₂Si
• Molecular Weight: 261.266
• Mol file: 217486-36-7.mol

Synonyms:dichlorophenyl(1,1,2-trimethylpropyl)silane

Chemical Property of dichlorophenyl(1,1,2-trimethylpropyl)silane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of dichlorophenyl(1,1,2-trimethylpropyl)silane

There total 1 articles about dichlorophenyl(1,1,2-trimethylpropyl)silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

bromobenzene (108-86-1,52753-63-6) + trichloro(2,3-dimethylbutan-2-yl)silane (18151-53-6) → dichlorophenyl(1,1,2-trimethylpropyl)silane (217486-36-7)

Guidance literature:

With lithium; Yield given. Multistep reaction; 1.) ether, 2 h, 2.) ether, room temp., 12 h;

DOI:10.1246/bcsj.71.2449

Reference yield: 19.0%

dichlorophenyl(1,1,2-trimethylpropyl)silane (217486-36-7) → 1,2,3-Triphenyl-1,2,3-tris-(1,1,2-trimethyl-propyl)-trisilirane (217486-25-4) + 1,2,3-Triphenyl-1,2,3-tris-(1,1,2-trimethyl-propyl)-trisilirane (217486-23-2)

Guidance literature:

With naphthalen-1-yl-lithium; In tetrahydrofuran; at -65 - 20 ℃;

DOI:10.1246/bcsj.71.2449

Reference yield:

dichlorophenyl(1,1,2-trimethylpropyl)silane (217486-36-7) → (S,S)-1,3-Dichloro-1,2,3-triphenyl-1,2,3-tris-(1,1,2-trimethyl-propyl)-trisilane

Guidance literature:

Multi-step reaction with 2 steps

1: 52 percent / lithium naphthalenide / tetrahydrofuran / -65 - 20 °C

2: Cl₂ / benzene / Ambient temperature

With chlorine; naphthalen-1-yl-lithium; In tetrahydrofuran; benzene;

DOI:10.1246/bcsj.71.2449

upstream raw materials:

bromobenzene

trichloro(2,3-dimethylbutan-2-yl)silane

Downstream raw materials:

1,2,3-Triphenyl-1,2,3-tris-(1,1,2-trimethyl-propyl)-trisilirane

1,2,3-Triphenyl-1,2,3-tris-(1,1,2-trimethyl-propyl)-trisilirane