(C₆H₅)2CCCCH(Ge(C₂H₅)3)

Base Information

Chemical Name:(C₆H₅)2CCCCH(Ge(C₂H₅)3)
CAS No.:79073-90-8
Molecular Formula:C₂₂H₂₆Ge
Molecular Weight:363.038
Hs Code.:

(C<sub>6</sub>H<sub>5</sub>)2CCCCH(Ge(C<sub>2</sub>H<sub>5</sub>)3)

Synonyms:(C₆H₅)2CCCCH(Ge(C₂H₅)3)

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Chemical Property of (C₆H₅)2CCCCH(Ge(C₂H₅)3)

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Technology Process of (C₆H₅)2CCCCH(Ge(C₂H₅)3)

There total 1 articles about (C₆H₅)2CCCCH(Ge(C₂H₅)3) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: 71451-08-6
Trifluoro-methanesulfonic acid 1-benzhydrylidene-prop-2-ynyl ester

: 1188-14-3
Triethylgerman

: 79073-90-8
(C₆H₅)2CCCCH(Ge(C₂H₅)3)

Guidance literature:: With t-butylnitrite; potassium tert-butylate; In 1,2-dimethoxyethane; under Ar excess Et3GeH and soln. of vinyl triflate in DME contg. 0.5 % w/v t-BuNO cooled to -50°C, soln. of t-BuOK in DME added dropwideover a 20-30 min; soln. neutralized, evapd., remaining sludge extd. with Ar-flushed pentane, pentane soln. dried over MgSO4, filtered, concd., chromd., from colorless front fraction pentane evapd.;
DOI:10.1021/ja00408a025

Reference yield: 71.0%

: 14694-95-2
Wilkinson's catalyst

: 79073-90-8
(C₆H₅)2CCCCH(Ge(C₂H₅)3)

: 87247-40-3,86420-16-8,86374-28-9
bis(triphenylphosphine)chloro(4,4-diphenyl-1-(triethylgermyl)-1,2,3-butatriene)rhodium

Guidance literature:: In benzene; Stang, P. J.; White, M. R.; Maas, G. Organometallics 1983, 2, 720-725; for 1-2 h at room temp.; chromd. (SiO2, CHCl3/CCl4), recrystd. from C6H6/hexane at room temp.; elem. anal.;

Reference yield:

: 12120-15-9
ethylenebis(triphenylphosphine)platinum⁽⁰⁾

: 79073-90-8
(C₆H₅)2CCCCH(Ge(C₂H₅)3)

: 87190-04-3
bis(triphenylphosphine)[η2-4,4-diphenyl-1-(triethylgermyl)-1,2,3-butatriene]platinum

: 87190-05-4
bis(triphenylphosphine)[η2-4,4-diphenyl-1-(triethylgermyl)-1,2,3-butatriene]platinum

Guidance literature:: In dichloromethane; complex was added to a soln. of triene, stirred for 15 min, Ar atm.; MeOH was added dropwise, cooling at -10°C overnight, ppt. was washed with cold MeOH, air-dried, not sep. mixture of isomers, detected byNMR spectrum; elem. anal.;