[2R,3S,(S)S]-N-{2-phenyl-3-triisopropylsilyloxy-3-[(S)-2-(p-toluenesulfinyl)phenyl]propyl}-p-toluenesulfinamide

Base Information

Chemical Name:[2R,3S,(S)S]-N-{2-phenyl-3-triisopropylsilyloxy-3-[(S)-2-(p-toluenesulfinyl)phenyl]propyl}-p-toluenesulfinamide
CAS No.:866993-65-9
Molecular Formula:C₃₈H₄₉NO₃S₂Si
Molecular Weight:660.029
Hs Code.:

Synonyms:[2R,3S,(S)S]-N-{2-phenyl-3-triisopropylsilyloxy-3-[(S)-2-(p-toluenesulfinyl)phenyl]propyl}-p-toluenesulfinamide

Suppliers and Price of [2R,3S,(S)S]-N-{2-phenyl-3-triisopropylsilyloxy-3-[(S)-2-(p-toluenesulfinyl)phenyl]propyl}-p-toluenesulfinamide

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of [2R,3S,(S)S]-N-{2-phenyl-3-triisopropylsilyloxy-3-[(S)-2-(p-toluenesulfinyl)phenyl]propyl}-p-toluenesulfinamide

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of [2R,3S,(S)S]-N-{2-phenyl-3-triisopropylsilyloxy-3-[(S)-2-(p-toluenesulfinyl)phenyl]propyl}-p-toluenesulfinamide

There total 1 articles about [2R,3S,(S)S]-N-{2-phenyl-3-triisopropylsilyloxy-3-[(S)-2-(p-toluenesulfinyl)phenyl]propyl}-p-toluenesulfinamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 55.0%

: 65440-68-8
[S-(E)]-(+)-N-α-methylbenzylidene-p-toluenesulfinamide

: 302934-11-8
(S)-2-(Triisopropylsyloxymethyl)phenyl p-tolylsulfoxide

: 866993-65-9
[2R,3S,(S)S]-N-{2-phenyl-3-triisopropylsilyloxy-3-[(S)-2-(p-toluenesulfinyl)phenyl]propyl}-p-toluenesulfinamide

Guidance literature:: (S)-2-(Triisopropylsyloxymethyl)phenyl p-tolylsulfoxide; With lithium diisopropyl amide; In tetrahydrofuran; hexane; at -78 ℃; for 0.5h;

[S-(E)]-(+)-N-α-methylbenzylidene-p-toluenesulfinamide; In tetrahydrofuran; hexane; at -78 ℃; for 0.0833333h;
DOI:10.1021/ja0515203

Reference yield:

: 866993-65-9
[2R,3S,(S)S]-N-{2-phenyl-3-triisopropylsilyloxy-3-[(S)-2-(p-toluenesulfinyl)phenyl]propyl}-p-toluenesulfinamide

: (1R,2S)-1-Methyl-1-phenyl-2-[2-((S)-toluene-4-sulfinyl)-phenyl]-2-triisopropylsilanyloxy-ethylamine

Guidance literature:: With trifluoroacetic acid; In methanol; for 3h;
DOI:10.1021/ja0515203

Reference yield:

: 866993-65-9
[2R,3S,(S)S]-N-{2-phenyl-3-triisopropylsilyloxy-3-[(S)-2-(p-toluenesulfinyl)phenyl]propyl}-p-toluenesulfinamide

: (2R,3S)-2,3-diphenyl-3-triisopropylsilyloxypropyl-2-amine

Guidance literature:: Multi-step reaction with 2 steps

1: TFA / methanol / 3 h

2: Raney-Ni / tetrahydrofuran / 2 h

With nickel; trifluoroacetic acid; In tetrahydrofuran; methanol;
DOI:10.1021/ja0515203