(S,Z)-2'-<5-<(triisopropylsilyl)oxy>-2-methylenecyclohexylidene>ethanol

Base Information

Chemical Name:(S,Z)-2'-<5-<(triisopropylsilyl)oxy>-2-methylenecyclohexylidene>ethanol
CAS No.:100928-01-6
Molecular Formula:C₁₈H₃₄O₂Si
Molecular Weight:310.552
Hs Code.:

Synonyms:(S,Z)-2'-<5-<(triisopropylsilyl)oxy>-2-methylenecyclohexylidene>ethanol

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (S,Z)-2'-<5-<(triisopropylsilyl)oxy>-2-methylenecyclohexylidene>ethanol

Chemical Property:

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Technology Process of (S,Z)-2'-<5-<(triisopropylsilyl)oxy>-2-methylenecyclohexylidene>ethanol

There total 3 articles about (S,Z)-2'-<5-<(triisopropylsilyl)oxy>-2-methylenecyclohexylidene>ethanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 13154-24-0
triisopropylsilyl chloride

: 100928-01-6
(S,Z)-2'-<5-<(triisopropylsilyl)oxy>-2-methylenecyclohexylidene>ethanol

Guidance literature:: Multi-step reaction with 2 steps

1: 83.3 percent / imidazole / dimethylformamide / 10 h / Ambient temperature

2: 1.) Pb(OAc)4, 2.) NaAlH₂(OCH₂CH₂OCH₃)2 / 1.) CH₂Cl₂, -15 deg C, 15 min, 2.) toluene, RT, 2 h

With 1H-imidazole; lead(IV) acetate; sodium bis(2-methoxyethoxy)aluminium dihydride; In N,N-dimethyl-formamide;
DOI:10.1021/jo00358a019

Reference yield:

: 84985-78-4
(4R,7aR)-1-((2R,5R,E)-5,6-dimethylhept-3-en-2-yl)-4-((R,Z)-1-hydroxy-2-((S)-5-hydroxy-2-methylenecyclohexylidene)ethyl)-7a-methyloctahydro-1H-inden-4-ol

: 100928-01-6
(S,Z)-2'-<5-<(triisopropylsilyl)oxy>-2-methylenecyclohexylidene>ethanol

Guidance literature:: Multi-step reaction with 2 steps

1: 83.3 percent / imidazole / dimethylformamide / 10 h / Ambient temperature

2: 1.) Pb(OAc)4, 2.) NaAlH₂(OCH₂CH₂OCH₃)2 / 1.) CH₂Cl₂, -15 deg C, 15 min, 2.) toluene, RT, 2 h

With 1H-imidazole; lead(IV) acetate; sodium bis(2-methoxyethoxy)aluminium dihydride; In N,N-dimethyl-formamide;
DOI:10.1021/jo00358a019

Reference yield:

: 100928-00-5
3β-O-(triisopropylsilyl)-7,8-dihydroxy-7,8-dihydrovitamin D2

: 55812-82-3,63730-57-4,63730-58-5,102281-42-5
(1R,3aR,4S,7aR)-7a-methyl-1-<(2E)-(1R,4R)-1,4,5-trimethyl-hex-2-enyl>-octahydro-1H-inden-4-ol

: 100928-01-6
(S,Z)-2'-<5-<(triisopropylsilyl)oxy>-2-methylenecyclohexylidene>ethanol

Guidance literature:: With lead(IV) acetate; sodium bis(2-methoxyethoxy)aluminium dihydride; Yield given. Multistep reaction. Yields of byproduct given; 1.) CH₂Cl₂, -15 deg C, 15 min, 2.) toluene, RT, 2 h;
DOI:10.1021/jo00358a019