(5S,6S,10S,E)-6-(4-methoxybenzyloxy)-12,12,13,13-tetramethyl-10-((S)-4-methyl-2-methylene-5-((2R,6R)-6-(prop-2-ynyl)-3,6-dihydro-2H-pyran-2-yl)pentyl)-5-((E)-2-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)vinyl)-2,4,11-trioxa-12-silatetradec-8-ene

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Chemical Name:(5S,6S,10S,E)-6-(4-methoxybenzyloxy)-12,12,13,13-tetramethyl-10-((S)-4-methyl-2-methylene-5-((2R,6R)-6-(prop-2-ynyl)-3,6-dihydro-2H-pyran-2-yl)pentyl)-5-((E)-2-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)vinyl)-2,4,11-trioxa-12-silatetradec-8-ene
CAS No.:1072083-40-9
Molecular Formula:C₄₅H₆₈O₇Si
Molecular Weight:749.116
Hs Code.:

(5S,6S,10S,E)-6-(4-methoxybenzyloxy)-12,12,13,13-tetramethyl-10-((S)-4-methyl-2-methylene-5-((2R,6R)-6-(prop-2-ynyl)-3,6-dihydro-2H-pyran-2-yl)pentyl)-5-((E)-2-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)vinyl)-2,4,11-trioxa-12-silatetradec-8-ene

Synonyms:(5S,6S,10S,E)-6-(4-methoxybenzyloxy)-12,12,13,13-tetramethyl-10-((S)-4-methyl-2-methylene-5-((2R,6R)-6-(prop-2-ynyl)-3,6-dihydro-2H-pyran-2-yl)pentyl)-5-((E)-2-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)vinyl)-2,4,11-trioxa-12-silatetradec-8-ene

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Chemical Property of (5S,6S,10S,E)-6-(4-methoxybenzyloxy)-12,12,13,13-tetramethyl-10-((S)-4-methyl-2-methylene-5-((2R,6R)-6-(prop-2-ynyl)-3,6-dihydro-2H-pyran-2-yl)pentyl)-5-((E)-2-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)vinyl)-2,4,11-trioxa-12-silatetradec-8-ene

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Technology Process of (5S,6S,10S,E)-6-(4-methoxybenzyloxy)-12,12,13,13-tetramethyl-10-((S)-4-methyl-2-methylene-5-((2R,6R)-6-(prop-2-ynyl)-3,6-dihydro-2H-pyran-2-yl)pentyl)-5-((E)-2-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)vinyl)-2,4,11-trioxa-12-silatetradec-8-ene

There total 1 articles about (5S,6S,10S,E)-6-(4-methoxybenzyloxy)-12,12,13,13-tetramethyl-10-((S)-4-methyl-2-methylene-5-((2R,6R)-6-(prop-2-ynyl)-3,6-dihydro-2H-pyran-2-yl)pentyl)-5-((E)-2-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)vinyl)-2,4,11-trioxa-12-silatetradec-8-ene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: (2S,6S)-2-(tert-butyldimethylsilyloxy)-6-methyl-4-methylene-7-((2R,6R)-6-(prop-2-ynyl)-3,6-dihydro-2H-pyran-2-yl)heptanal

: 385809-23-4
[(2S),3S,4S,5E]-5-{3-(4-methoxybenzyloxy)-4-methoxymethoxy-6-[4-methyl-3,6-dihydro-2H-pyran-2-yl]-hex-5-enyl-1-sulfonyl}-1-phenyl-1H-tetrazol

: 1072083-40-9
(5S,6S,10S,E)-6-(4-methoxybenzyloxy)-12,12,13,13-tetramethyl-10-((S)-4-methyl-2-methylene-5-((2R,6R)-6-(prop-2-ynyl)-3,6-dihydro-2H-pyran-2-yl)pentyl)-5-((E)-2-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)vinyl)-2,4,11-trioxa-12-silatetradec-8-ene

Guidance literature:: [(2S),3S,4S,5E]-5-{3-(4-methoxybenzyloxy)-4-methoxymethoxy-6-[4-methyl-3,6-dihydro-2H-pyran-2-yl]-hex-5-enyl-1-sulfonyl}-1-phenyl-1H-tetrazol; With potassium hexamethylsilazane; In tetrahydrofuran; toluene; at -78 ℃; for 0.133333h;

(2S,6S)-2-(tert-butyldimethylsilyloxy)-6-methyl-4-methylene-7-((2R,6R)-6-(prop-2-ynyl)-3,6-dihydro-2H-pyran-2-yl)heptanal; In tetrahydrofuran; toluene; at -78 ℃; for 1.58333h;
DOI:10.1021/ol802075v