1-Iodo-2,3,4,5-tetramethylbenzene

Base Information

Chemical Name:1-Iodo-2,3,4,5-tetramethylbenzene
CAS No.:54509-71-6
Molecular Formula:C10H13 I
Molecular Weight: 260.11
Hs Code.:2903999090
DSSTox Substance ID:DTXSID70380301
Wikidata:Q82170486
Mol file:54509-71-6.mol

Synonyms:1-iodo-2,3,4,5-tetramethylbenzene;54509-71-6;2,3,4,5-Tetramethyliodobenzene;SCHEMBL4175398;DTXSID70380301;PSTRAAIJGQNXGR-UHFFFAOYSA-N;CYCLOHEXYL3-MERCAPTOPROPIONATE;AKOS025295452;FT-0607945

Suppliers and Price of 1-Iodo-2,3,4,5-tetramethylbenzene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

American Custom Chemicals Corporation
1-IODO-2,3,4,5-TETRAMETHYLBENZENE 95.00%
25G
$ 1450.45

American Custom Chemicals Corporation
1-IODO-2,3,4,5-TETRAMETHYLBENZENE 95.00%
5G
$ 878.03

AHH
2,3,4,5-Tetramethyliodobenzene 98%
50g
$ 320.00

Total 8 raw suppliers

Chemical Property of 1-Iodo-2,3,4,5-tetramethylbenzene

Chemical Property:

Vapor Pressure:0.00733mmHg at 25°C
Melting Point:30 °C
Boiling Point:278.1°C at 760 mmHg
Flash Point:124°C
PSA：0.00000
Density:1.472g/cm³
LogP:3.52480
Sensitive.:Light Sensitive
XLogP3:4.8
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:0
Exact Mass:260.00620
Heavy Atom Count:11
Complexity:133

Purity/Quality:

99% ^*data from raw suppliers

1-IODO-2,3,4,5-TETRAMETHYLBENZENE 95.00% ^*data from reagent suppliers

Safty Information:

Pictogram(s): Xi,Xn
Hazard Codes:Xi,Xn
Safety Statements: S24/25:Avoid contact with skin and eyes.;

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1=CC(=C(C(=C1C)C)C)I

Technology Process of 1-Iodo-2,3,4,5-tetramethylbenzene

There total 1 articles about 1-Iodo-2,3,4,5-tetramethylbenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: 488-23-3
1,2,3,4-Tetramethylbenzene

: 54509-71-6
1-iodo-2,3,4,5-tetramethylbenzene

Guidance literature:: With sulfuric acid; iodine; nitric acid; In acetic acid; at 50 - 55 ℃; for 5h;

Reference yield:

: 54509-71-6
1-iodo-2,3,4,5-tetramethylbenzene

: 173327-56-5
3,5-bis-O,O-(tert-butyldimethylsilyl)-1,2-didehydro-1,2-dideoxy-D-ribofuranose

: 3-(tert-butyl-dimethyl-silanyloxy)-2-(tert-butyl-dimethyl-silanyloxymethyl)-5-(2,3,4,5-tetramethyl-phenyl)-2,5-dihydro-furan

Guidance literature:: With tributyl-amine; triphenyl-arsane; palladium diacetate; In N,N-dimethyl-formamide; at 70 ℃; for 16h;
DOI:10.1021/ja047291m

Reference yield:

: 54509-71-6
1-iodo-2,3,4,5-tetramethylbenzene

: (2R,5R)-2-Hydroxymethyl-5-(2,3,4,5-tetramethyl-phenyl)-dihydro-furan-3-one

Guidance literature:: Multi-step reaction with 2 steps

1: palladium acetate; triphenylarsine; tri-n-butylamine / dimethylformamide / 16 h / 70 °C

2: tetra-n-butylammonium fluoride; AcOH / tetrahydrofuran; dimethylformamide / 1 h / 0 °C

With tributyl-amine; triphenyl-arsane; tetrabutyl ammonium fluoride; palladium diacetate; acetic acid; In tetrahydrofuran; N,N-dimethyl-formamide; 1: Heck reaction;
DOI:10.1021/ja047291m