[5-(3-iodophenyl)-15-(4-[tri-iso-propylsilylethynyl]phenyl)-3,7,13,17-tetrabutyl-2,8,12,18-tetramethylporphyrinato]zinc

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Chemical Name:[5-(3-iodophenyl)-15-(4-[tri-iso-propylsilylethynyl]phenyl)-3,7,13,17-tetrabutyl-2,8,12,18-tetramethylporphyrinato]zinc
CAS No.:1237507-08-2
Molecular Formula:C₆₃H₇₉IN₄SiZn
Molecular Weight:1112.73
Hs Code.:

Synonyms:[5-(3-iodophenyl)-15-(4-[tri-iso-propylsilylethynyl]phenyl)-3,7,13,17-tetrabutyl-2,8,12,18-tetramethylporphyrinato]zinc

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Chemical Property of [5-(3-iodophenyl)-15-(4-[tri-iso-propylsilylethynyl]phenyl)-3,7,13,17-tetrabutyl-2,8,12,18-tetramethylporphyrinato]zinc

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Technology Process of [5-(3-iodophenyl)-15-(4-[tri-iso-propylsilylethynyl]phenyl)-3,7,13,17-tetrabutyl-2,8,12,18-tetramethylporphyrinato]zinc

There total 1 articles about [5-(3-iodophenyl)-15-(4-[tri-iso-propylsilylethynyl]phenyl)-3,7,13,17-tetrabutyl-2,8,12,18-tetramethylporphyrinato]zinc which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 28.0%

: 696-41-3
m-iodobenzaldehyde

: 116748-68-6
bis(3-butyl-4-methyl-2-pyrrolyl)methane

: 307930-42-3
4-[2-(triisopropylsilyl)ethynyl]benzaldehyde

: 1237507-07-1
[5,15-bis(3-iodophenyl)-3,7,13,17-tetrabutyl-2,8,12,18-tetramethylporphyrinato]zinc

: 1237507-08-2
[5-(3-iodophenyl)-15-(4-[tri-iso-propylsilylethynyl]phenyl)-3,7,13,17-tetrabutyl-2,8,12,18-tetramethylporphyrinato]zinc

: [5,15-bis(4-[tri-iso-propylsilylethynyl]phenyl)-3,7,13,17-tetrabutyl-2,8,12,18-tetramethylporphyrinato]zinc

Guidance literature:: m-iodobenzaldehyde; bis(3-butyl-4-methyl-2-pyrrolyl)methane; 4-[2-(triisopropylsilyl)ethynyl]benzaldehyde; With trifluoroacetic acid; In dichloromethane; at 20 ℃; for 3h; Inert atmosphere;

With 2,3-dicyano-5,6-dichloro-p-benzoquinone; In dichloromethane; at 20 ℃; for 0.5h; Inert atmosphere;

With zinc(II) acetate dihydrate; In methanol; dichloromethane; at 20 ℃; for 1h; Inert atmosphere;
DOI:10.1021/ol101393h

Reference yield: 50.0%

: 1237507-08-2
[5-(3-iodophenyl)-15-(4-[tri-iso-propylsilylethynyl]phenyl)-3,7,13,17-tetrabutyl-2,8,12,18-tetramethylporphyrinato]zinc

: 1237507-06-0
[5,15-bis-(3-pinacolboranphenyl)-3,7,13,17-tetrabutyl-2,8,12,18-tetramethylporphyrinato]zinc

: 1237507-05-9
[5,15-bis(4-[tri-iso-propylsilylethynyl]phenyl)-3,7,13,17-tetrabutyl-2,8,12,18-tetramethylporphyrinato]zinc-[([1,1'-biphenyl]-3-yl)-3,7,13,17-tetrabutyl-2,8,12,18-tetramethylporphyrinato]zinc

Guidance literature:: [5-(3-iodophenyl)-15-(4-[tri-iso-propylsilylethynyl]phenyl)-3,7,13,17-tetrabutyl-2,8,12,18-tetramethylporphyrinato]zinc; [5,15-bis-(3-pinacolboranphenyl)-3,7,13,17-tetrabutyl-2,8,12,18-tetramethylporphyrinato]zinc; With pyridine; dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH₂Cl₂; In toluene;

With caesium carbonate; In water; N,N-dimethyl-formamide; toluene; at 60 ℃; Inert atmosphere; Cooling;
DOI:10.1021/ol101393h