3((C₆H₅)3P)2N⁽¹⁺⁾*Rh₁₅^(3-)*27CO=(((C₆H₅)3P)2N)3(Rh₁₅(CO)27)

Base Information

• Chemical Name: 3((C₆H₅)3P)2N⁽¹⁺⁾*Rh₁₅^(3-)*27CO=(((C₆H₅)3P)2N)3(Rh₁₅(CO)27)
• CAS No.: 75506-17-1
• Molecular Formula: 27CO*3C₃₆H₃₀NP₂*Rh₁₅
• Molecular Weight: 3915.63

Synonyms:3((C₆H₅)3P)2N⁽¹⁺⁾*Rh₁₅^(3-)*27CO=(((C₆H₅)3P)2N)3(Rh₁₅(CO)27)

Chemical Property of 3((C₆H₅)3P)2N⁽¹⁺⁾*Rh₁₅^(3-)*27CO=(((C₆H₅)3P)2N)3(Rh₁₅(CO)27)

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Technology Process of 3((C₆H₅)3P)2N⁽¹⁺⁾*Rh₁₅^(3-)*27CO=(((C₆H₅)3P)2N)3(Rh₁₅(CO)27)

There total 2 articles about 3((C₆H₅)3P)2N⁽¹⁺⁾*Rh₁₅^(3-)*27CO=(((C₆H₅)3P)2N)3(Rh₁₅(CO)27) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

acetylacetonatodicarbonylrhodium(l) + cesium benzoate dihydrate + bis(triphenylphosphine)iminium chloride (21050-13-5) → 3((C6H5)3P)2N(1+)*Rh15(3-)*27CO=(((C6H5)3P)2N)3(Rh15(CO)27) (75506-17-1)

Guidance literature:

With 4-methyl-morpholine; In ethylene glycol; High Pressure; ethylene glycol and N-methylmorpholine addn. to Rh(CO)2(acac) and Cs-benzoate soln. in tetraglyme; quickly heated to 150°C in 10 atm (CO/H2); 1 h 19 atm at 150°C (CO/H2); vented; filtered; filtrate cooled; toluene addn.; decanted; washed with 2-propanol; dissolved in acetone; filtered; ((Ph3P)2N)Cl addn. in 2-propanol; ppt. filtered, washed with 2-propanol; vac. dried; elem. anal.;

Reference yield:

acetylacetonatodicarbonylrhodium(l) + bis(triphenylphosphine)iminium chloride (21050-13-5) → 3((C6H5)3P)2N(1+)*Rh15(3-)*27CO=(((C6H5)3P)2N)3(Rh15(CO)27) (75506-17-1)

Guidance literature:

With cesium benzoate; In ethylene glycol; High Pressure; tetraethylene glycol dimethyl ether, reaction mixture was stirred for 0.5 h under Ar, after charging to the high-pressure autoclave, pessurizedwith equimolar mixture of CO/H2, 1 h at 140-160°C and 12-15 atm;

DOI:10.1016/S0022-328X(00)86104-5

Reference yield: 82.0%

3((C6H5)3P)2N(1+)*Rh15(3-)*27CO=(((C6H5)3P)2N)3(Rh15(CO)27) (75506-17-1) + 3[(C6H5)3P]2N(1+)*[Rh7](3-)*16CO=[[(C6H5)3P]2N]3[Rh7(CO)16] → 2[(C6H5)3P]2N(1+)*[Rh14](2-)*26CO=[[(C6H5)3P]2N]2[Rh14(CO)26]

Guidance literature:

With trifluoromethylsulfonic acid; In acetone; at 0°C was added the reagent to the starting material; pptn. with isopropanol, extn. with acetone, and repptn. with hexane, elem. anal.;

DOI:10.1016/S0022-328X(00)86104-5

upstream raw materials:

bis(triphenylphosphine)iminium chloride

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