(1,4,5,6-tetraphenyl-2,3-benzo-7-methyl-7-silanorbornadienyl)cyclopentadienyldicarbonyliron

Base Information

• Chemical Name: (1,4,5,6-tetraphenyl-2,3-benzo-7-methyl-7-silanorbornadienyl)cyclopentadienyldicarbonyliron
• CAS No.: 105311-75-9
• Molecular Formula: C₄₂H₃₂FeO₂Si
• Molecular Weight: 652.647
• Mol file: 105311-75-9.mol

Synonyms:(1,4,5,6-tetraphenyl-2,3-benzo-7-methyl-7-silanorbornadienyl)cyclopentadienyldicarbonyliron

Chemical Property of (1,4,5,6-tetraphenyl-2,3-benzo-7-methyl-7-silanorbornadienyl)cyclopentadienyldicarbonyliron

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (1,4,5,6-tetraphenyl-2,3-benzo-7-methyl-7-silanorbornadienyl)cyclopentadienyldicarbonyliron

There total 1 articles about (1,4,5,6-tetraphenyl-2,3-benzo-7-methyl-7-silanorbornadienyl)cyclopentadienyldicarbonyliron which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

o-fluorobromobenzene (1072-85-1) + (1-methyl-2,3,4,5-tetraphenyl-1-silacyclopentadienyl)cyclopentadienyldicarbonyliron (105311-74-8) → (1,4,5,6-tetraphenyl-2,3-benzo-7-methyl-7-silanorbornadienyl)cyclopentadienyldicarbonyliron (105311-75-9)

Guidance literature:

With magnesium; In tetrahydrofuran; 2-bromofluorobenzene added to a mixt. of Fe-complex and Mg turnings in THF at 0°C with stirring under N2, mixt. was warmed to room temp. and stirred for 24 h; evapn. of THF, residue dissolved in CH2Cl2, filtered, filtrate chromd. on SiO2 under N2 (eluant hexane/ether (90/10)); elem. anal.;

DOI:10.1021/om00144a025

Reference yield:

(1,4,5,6-tetraphenyl-2,3-benzo-7-methyl-7-silanorbornadienyl)cyclopentadienyldicarbonyliron (105311-75-9) + trans,trans-1,4-Diphenyl-1,3-butadiene (886-65-7,538-81-8) → C5H5(CO)2FeSi(CH3)C4H4(C6H5)2 (105311-80-6)

Guidance literature:

In xylene; heated at 180°C in a sealed tube for 7 h; small amount of the product formed;

DOI:10.1021/om00144a025

upstream raw materials:

o-fluorobromobenzene

(1-methyl-2,3,4,5-tetraphenyl-1-silacyclopentadienyl)cyclopentadienyldicarbonyliron

Downstream raw materials:

C₅H₅(CO)2FeSi(CH₃)C₄H₄(C₆H₅)2