1,6-Anhydro-2-azido-3-O-benzyl-4-O-(2,4-di-O-benzyl-β-D-mannopyranosyl)-2-desoxy-β-D-glucopyranose

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Chemical Name:1,6-Anhydro-2-azido-3-O-benzyl-4-O-(2,4-di-O-benzyl-β-D-mannopyranosyl)-2-desoxy-β-D-glucopyranose
CAS No.:83259-15-8
Molecular Formula:C₃₃H₃₇N₃O₉
Molecular Weight:619.671
Hs Code.:

Synonyms:1,6-Anhydro-2-azido-3-O-benzyl-4-O-(2,4-di-O-benzyl-β-D-mannopyranosyl)-2-desoxy-β-D-glucopyranose

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Chemical Property of 1,6-Anhydro-2-azido-3-O-benzyl-4-O-(2,4-di-O-benzyl-β-D-mannopyranosyl)-2-desoxy-β-D-glucopyranose

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Technology Process of 1,6-Anhydro-2-azido-3-O-benzyl-4-O-(2,4-di-O-benzyl-β-D-mannopyranosyl)-2-desoxy-β-D-glucopyranose

There total 9 articles about 1,6-Anhydro-2-azido-3-O-benzyl-4-O-(2,4-di-O-benzyl-β-D-mannopyranosyl)-2-desoxy-β-D-glucopyranose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 83259-20-5
4-O-(6-O-Acetyl-2,4-di-O-benzyl-β-D-mannopyranosyl-1,6-anhydro-2-azido-3-O-benzyl-2-desoxy-β-D-glucopyranose

: 83259-15-8
1,6-Anhydro-2-azido-3-O-benzyl-4-O-(2,4-di-O-benzyl-β-D-mannopyranosyl)-2-desoxy-β-D-glucopyranose

Guidance literature:: With sodium methylate; In methanol; for 1h;

Reference yield:

: 55682-57-0
1,6-anhydro-2-azido-3-O-benzyl-2-deoxy-β-D-glucopyranose

: 83259-15-8
1,6-Anhydro-2-azido-3-O-benzyl-4-O-(2,4-di-O-benzyl-β-D-mannopyranosyl)-2-desoxy-β-D-glucopyranose

Guidance literature:: Multi-step reaction with 3 steps

1: 1) silver silicat, molecular sieve (4 Angstroem) / 1) CH₂Cl₂, 2 h, room temp.; 2) 3 h, CH₂Cl₂

2: 1) (PPh₃)3Rh(I)Cl, 1,4-diazabicyclo<2.2.2>octane; 2) HgCl₂, HgO / 1) ethanol,toluene, water,8 h, room temp.; 2) acetone, water, 30 min, room temp.

3: 94 percent / sodium methylate / methanol / 1 h

With 1,4-diaza-bicyclo[2.2.2]octane; Wilkinson's catalyst; silver silicate; 4 A molecular sieve; sodium methylate; mercury dichloride; mercury(II) oxide; In methanol;

Reference yield:

: 83259-13-6
6-O-acetyl-3-O-allyl-2,4-di-O-benzyl-α-D-mannopyranosyl bromide

: 83259-15-8
1,6-Anhydro-2-azido-3-O-benzyl-4-O-(2,4-di-O-benzyl-β-D-mannopyranosyl)-2-desoxy-β-D-glucopyranose

Guidance literature:: Multi-step reaction with 3 steps

1: 1) silver silicat, molecular sieve (4 Angstroem) / 1) CH₂Cl₂, 2 h, room temp.; 2) 3 h, CH₂Cl₂

2: 1) (PPh₃)3Rh(I)Cl, 1,4-diazabicyclo<2.2.2>octane; 2) HgCl₂, HgO / 1) ethanol,toluene, water,8 h, room temp.; 2) acetone, water, 30 min, room temp.

3: 94 percent / sodium methylate / methanol / 1 h

With 1,4-diaza-bicyclo[2.2.2]octane; Wilkinson's catalyst; silver silicate; 4 A molecular sieve; sodium methylate; mercury dichloride; mercury(II) oxide; In methanol;