C-{(S)-C-[(2S,3S)-3-(tert-Butyl-dimethyl-silanyloxymethyl)-oxiranyl]-C-phenyl}-methylamine

Base Information

Chemical Name:C-{(S)-C-[(2S,3S)-3-(tert-Butyl-dimethyl-silanyloxymethyl)-oxiranyl]-C-phenyl}-methylamine
CAS No.:143216-56-2
Molecular Formula:C₁₆H₂₇NO₂Si
Molecular Weight:293.481
Hs Code.:

Synonyms:C-{(S)-C-[(2S,3S)-3-(tert-Butyl-dimethyl-silanyloxymethyl)-oxiranyl]-C-phenyl}-methylamine

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Chemical Property of C-{(S)-C-[(2S,3S)-3-(tert-Butyl-dimethyl-silanyloxymethyl)-oxiranyl]-C-phenyl}-methylamine

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Technology Process of C-{(S)-C-[(2S,3S)-3-(tert-Butyl-dimethyl-silanyloxymethyl)-oxiranyl]-C-phenyl}-methylamine

There total 1 articles about C-{(S)-C-[(2S,3S)-3-(tert-Butyl-dimethyl-silanyloxymethyl)-oxiranyl]-C-phenyl}-methylamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 134869-78-6
(2S,3S)-3-cyano-2,3-epoxy-1-propanol TBS ether

: phenylmagnesium bromide

: 143290-32-8
C-{(R)-C-[(2S,3S)-3-(tert-Butyl-dimethyl-silanyloxymethyl)-oxiranyl]-C-phenyl}-methylamine

: 143216-56-2
C-{(S)-C-[(2S,3S)-3-(tert-Butyl-dimethyl-silanyloxymethyl)-oxiranyl]-C-phenyl}-methylamine

Guidance literature:: With sodium tetrahydroborate; chloro-trimethyl-silane; Product distribution; Mechanism; multistep reaction; other hydrides, other Grignard reagents, chiral α,β-epoxy group as a stereocontrolling element in reduction of N-metalloimines;
DOI:10.1021/jo00045a006

Reference yield: 92.0%

: 143216-56-2
C-{(S)-C-[(2S,3S)-3-(tert-Butyl-dimethyl-silanyloxymethyl)-oxiranyl]-C-phenyl}-methylamine

: 143216-61-9
(2S,3S,4S)-4-amino-2,3-epoxy-4-phenyl-1-butanol

Guidance literature:: With tetrabutyl ammonium fluoride; In tetrahydrofuran; for 0.5h; Ambient temperature;
DOI:10.1016/0040-4020(92)80014-7

Reference yield:

: 143216-56-2
C-{(S)-C-[(2S,3S)-3-(tert-Butyl-dimethyl-silanyloxymethyl)-oxiranyl]-C-phenyl}-methylamine

: 143602-14-6
(2R,3R,4S)-3,4-imino-4-phenyl-1,2-butanediol

Guidance literature:: Multi-step reaction with 2 steps

1: 92 percent / TBAF / tetrahydrofuran / 0.5 h / Ambient temperature

2: 63 percent / Ti(O-i-Pr)4 / tetrahydrofuran / 1 h / Ambient temperature

With titanium(IV) isopropylate; tetrabutyl ammonium fluoride; In tetrahydrofuran;
DOI:10.1016/0040-4020(92)80014-7