Ni(C₅H₅)P(C₆H₅)3CH₂S(CH₃)2⁽¹⁺⁾*PF₆^(1-)

Base Information

Chemical Name:Ni(C₅H₅)P(C₆H₅)3CH₂S(CH₃)2⁽¹⁺⁾*PF₆^(1-)
CAS No.:80507-32-0
Molecular Formula:C₂₆H₂₈NiPS*F₆P
Molecular Weight:607.202
Hs Code.:

Ni(C<sub>5</sub>H<sub>5</sub>)P(C<sub>6</sub>H<sub>5</sub>)3CH<sub>2</sub>S(CH<sub>3</sub>)2<sup>(1+)</sup>*PF<sub>6</sub><sup>(1-)</sup>

Synonyms:Ni(C₅H₅)P(C₆H₅)3CH₂S(CH₃)2⁽¹⁺⁾*PF₆^(1-)

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Ni(C₅H₅)P(C₆H₅)3CH₂S(CH₃)2⁽¹⁺⁾*PF₆^(1-)

Chemical Property:

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Technology Process of Ni(C₅H₅)P(C₆H₅)3CH₂S(CH₃)2⁽¹⁺⁾*PF₆^(1-)

There total 2 articles about Ni(C₅H₅)P(C₆H₅)3CH₂S(CH₃)2⁽¹⁺⁾*PF₆^(1-) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 23.0%

: ammonium hexafluorophosphate

: 6814-64-8,40651-06-7
methylenedimethyl sulfurane

NiBr(η(5)-cyclopentadienyl)(triphenylphosphine-P): NiBr(η(5)-cyclopentadienyl)(triphenylphosphine-P)

: 80507-32-0
Ni(C₅H₅)P(C₆H₅)3CH₂S(CH₃)2⁽¹⁺⁾*PF₆^(1-)

Guidance literature:: In tetrahydrofuran; diethyl ether; water; methylid in THF was added to the soln. of the Ni-complex in Et2O and stirred at 0°C for 2 h under N2,Et2O was removed, filtration, treatment of the filtrate with NH4PF6 in water; ppt. recrystd. from aq. ethanol; elem. anal.;
DOI:10.1016/S0022-328X(00)90110-4

Reference yield:

: ammonium hexafluorophosphate

: 6814-64-8,40651-06-7
methylenedimethyl sulfurane

: chloro(cyclopentadienyl)(triphenylphosphine)nickel(II)

: 96348-95-7
(Ni(C₅H₅)P(C₆H₅)3CH₂)2S(CH₃)⁽¹⁺⁾*PF₆^(1-)

: 80507-32-0
Ni(C₅H₅)P(C₆H₅)3CH₂S(CH₃)2⁽¹⁺⁾*PF₆^(1-)

Guidance literature:: In tetrahydrofuran; water; acetone; to soln. of complex in THF at -78°C soln. of 1 equiv of Me2SCH2 was introduced, mixt. was stirred for ca. 0.5 h at -78°, then rapidly warmed to room temp., filtered, ether was added, aq. NH4PF6 was added to acetone soln.(N2); ppt. was filtered, washed with water, dried under vac., fractional crystn. from H2O-acetone; elem. anal.;
DOI:10.1021/om00126a007