14R,16-bis-(tert-butyldimethylsilanyloxy)-6S-(4-methoxybenzyloxy)-5S,7R,13S,15S-tetramethylhexadeca-3Z,9E-dien-8-one

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Chemical Name:14R,16-bis-(tert-butyldimethylsilanyloxy)-6S-(4-methoxybenzyloxy)-5S,7R,13S,15S-tetramethylhexadeca-3Z,9E-dien-8-one
CAS No.:1234501-13-3
Molecular Formula:C₄₀H₇₂O₅Si₂
Molecular Weight:689.18
Hs Code.:

Synonyms:14R,16-bis-(tert-butyldimethylsilanyloxy)-6S-(4-methoxybenzyloxy)-5S,7R,13S,15S-tetramethylhexadeca-3Z,9E-dien-8-one

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Chemical Property of 14R,16-bis-(tert-butyldimethylsilanyloxy)-6S-(4-methoxybenzyloxy)-5S,7R,13S,15S-tetramethylhexadeca-3Z,9E-dien-8-one

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Technology Process of 14R,16-bis-(tert-butyldimethylsilanyloxy)-6S-(4-methoxybenzyloxy)-5S,7R,13S,15S-tetramethylhexadeca-3Z,9E-dien-8-one

There total 1 articles about 14R,16-bis-(tert-butyldimethylsilanyloxy)-6S-(4-methoxybenzyloxy)-5S,7R,13S,15S-tetramethylhexadeca-3Z,9E-dien-8-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 1234501-03-1
5R,7-bis(tert-butyldimethylsilyloxy)-4S,6S-dimethylheptanal

: 1234501-01-9
[4S-(4-methoxybenzyloxy)-3R,5S-dimethyl-2-oxonon-6Z-enyl]-phosphonic acid di-methyl ester

: 1234501-13-3
14R,16-bis-(tert-butyldimethylsilanyloxy)-6S-(4-methoxybenzyloxy)-5S,7R,13S,15S-tetramethylhexadeca-3Z,9E-dien-8-one

Guidance literature:: [4S-(4-methoxybenzyloxy)-3R,5S-dimethyl-2-oxonon-6Z-enyl]-phosphonic acid di-methyl ester; With barium(II) hydroxide; In tetrahydrofuran; at 20 ℃; for 0.5h; Inert atmosphere;

5R,7-bis(tert-butyldimethylsilyloxy)-4S,6S-dimethylheptanal; In tetrahydrofuran; water; at 20 ℃; for 12h; Inert atmosphere;
DOI:10.1021/ja103537u

Reference yield: 95.0%

: 1234501-13-3
14R,16-bis-(tert-butyldimethylsilanyloxy)-6S-(4-methoxybenzyloxy)-5S,7R,13S,15S-tetramethylhexadeca-3Z,9E-dien-8-one

: 1234501-69-9
14R,16-bis-(tert-butyldimethylsilanyloxy)-6S-(4-methoxybenzyloxy)-5S,7R,13S,15S-tetramethylhexadec-3Z-en-8-one

Guidance literature:: With (triphenylphosphine)copper(I) hydride hexamer; In toluene; at 20 ℃; for 1h; Inert atmosphere;
DOI:10.1021/ja103537u