(3S,4S,6R)-6-(acetyloxy)-4-{[(tert-butyl)diphenylsilyl]oxy}hept-1-en-3-yl acrylate

Base Information

Chemical Name:(3S,4S,6R)-6-(acetyloxy)-4-{[(tert-butyl)diphenylsilyl]oxy}hept-1-en-3-yl acrylate
CAS No.:1393927-35-9
Molecular Formula:C₂₈H₃₆O₅Si
Molecular Weight:480.676
Hs Code.:

Synonyms:(3S,4S,6R)-6-(acetyloxy)-4-{[(tert-butyl)diphenylsilyl]oxy}hept-1-en-3-yl acrylate

Suppliers and Price of (3S,4S,6R)-6-(acetyloxy)-4-{[(tert-butyl)diphenylsilyl]oxy}hept-1-en-3-yl acrylate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (3S,4S,6R)-6-(acetyloxy)-4-{[(tert-butyl)diphenylsilyl]oxy}hept-1-en-3-yl acrylate

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Technology Process of (3S,4S,6R)-6-(acetyloxy)-4-{[(tert-butyl)diphenylsilyl]oxy}hept-1-en-3-yl acrylate

There total 8 articles about (3S,4S,6R)-6-(acetyloxy)-4-{[(tert-butyl)diphenylsilyl]oxy}hept-1-en-3-yl acrylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 1393927-26-8
(2R,4S,5S)-4-{[(tert-Butyl)diphenylsilyl]oxy}-5-hydroxyhept-6-en-2-yl acetate

: 814-68-6,25189-84-8
acryloyl chloride

: 1393927-35-9
(3S,4S,6R)-6-(acetyloxy)-4-{[(tert-butyl)diphenylsilyl]oxy}hept-1-en-3-yl acrylate

Guidance literature:: With N-ethyl-N,N-diisopropylamine; In dichloromethane; at 0 ℃; for 5h; Inert atmosphere;
DOI:10.1002/hlca.201100512

Reference yield:

: 1393927-33-7
(2R,4S)-5-{[(tert-butyl)dimethylsilyl]oxy}-4-{[(tert-butyl)diphenylsilyl]oxy}pentan-2-yl acetate

: 1393927-35-9
(3S,4S,6R)-6-(acetyloxy)-4-{[(tert-butyl)diphenylsilyl]oxy}hept-1-en-3-yl acrylate

Guidance literature:: Multi-step reaction with 4 steps

1.1: pyridinium p-toluenesulfonate / methanol / 12 h / 0 - 20 °C

2.1: pyridinium chlorochromate / dichloromethane / 5 h / 20 °C

3.1: magnesium bromide ethyl etherate / dichloromethane / 1 h

3.2: 12.25 h / -20 °C

4.1: N-ethyl-N,N-diisopropylamine / dichloromethane / 5 h / 0 °C / Inert atmosphere

With pyridinium p-toluenesulfonate; magnesium bromide ethyl etherate; N-ethyl-N,N-diisopropylamine; pyridinium chlorochromate; In methanol; dichloromethane;
DOI:10.1002/hlca.201100512

Reference yield:

: 1393927-38-2
C₂₃H₃₀O₄Si

: 1393927-35-9
(3S,4S,6R)-6-(acetyloxy)-4-{[(tert-butyl)diphenylsilyl]oxy}hept-1-en-3-yl acrylate

Guidance literature:: Multi-step reaction with 2 steps

1.1: magnesium bromide ethyl etherate / dichloromethane / 1 h

1.2: 12.25 h / -20 °C

2.1: N-ethyl-N,N-diisopropylamine / dichloromethane / 5 h / 0 °C / Inert atmosphere

With magnesium bromide ethyl etherate; N-ethyl-N,N-diisopropylamine; In dichloromethane;
DOI:10.1002/hlca.201100512