2,2-di-oct-7-enyl-malonic acid benzyl ester tert-butyl ester

Base Information

• Chemical Name: 2,2-di-oct-7-enyl-malonic acid benzyl ester tert-butyl ester
• CAS No.: 680197-76-6
• Molecular Formula: C₃₀H₄₆O₄
• Molecular Weight: 470.693
• Mol file: 680197-76-6.mol

Synonyms:2,2-di-oct-7-enyl-malonic acid benzyl ester tert-butyl ester

Chemical Property of 2,2-di-oct-7-enyl-malonic acid benzyl ester tert-butyl ester

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of 2,2-di-oct-7-enyl-malonic acid benzyl ester tert-butyl ester

There total 4 articles about 2,2-di-oct-7-enyl-malonic acid benzyl ester tert-butyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

8-Bromo-1-octene (2695-48-9) + 1-benzyl 3-(tert-butyl) malonate (72594-86-6) → 2-oct-7-enyl-malonic acid benzyl ester tert-butyl ester (680197-67-5) + 2,2-di-oct-7-enyl-malonic acid benzyl ester tert-butyl ester (680197-76-6)

Guidance literature:

With sodium hydride; In dimethyl sulfoxide; at 20 ℃;

DOI:10.1002/chem.200305492

Reference yield: 64.0%

8-Bromo-1-octene (2695-48-9) + 2-oct-7-enyl-malonic acid benzyl ester tert-butyl ester (680197-67-5) → 2,2-di-oct-7-enyl-malonic acid benzyl ester tert-butyl ester (680197-76-6)

Guidance literature:

With sodium hydride; In dimethyl sulfoxide; at 20 ℃;

DOI:10.1002/chem.200305492

Reference yield:

8-Bromo-1-octene (2695-48-9) → 2,2-di-oct-7-enyl-malonic acid benzyl ester tert-butyl ester (680197-76-6)

Guidance literature:

Multi-step reaction with 2 steps

1: 67 percent / NaH / dimethylsulfoxide / 20 °C

2: 64 percent / NaH / dimethylsulfoxide / 20 °C

With sodium hydride; In dimethyl sulfoxide;

DOI:10.1002/chem.200305492

upstream raw materials:

8-Bromo-1-octene

1-benzyl 3-(tert-butyl) malonate

2-oct-7-enyl-malonic acid benzyl ester tert-butyl ester

Downstream raw materials:

tert-butyl 1-(benzyloxycarbonyl)cyclopentadec-8-ene carboxylate