benzyl 4,4¹-anhydro-2,3,6-tri-O-benzyl-4-C-hydroxymethyl-α-D-glucopyranoside

Base Information

• Chemical Name: benzyl 4,4¹-anhydro-2,3,6-tri-O-benzyl-4-C-hydroxymethyl-α-D-glucopyranoside
• CAS No.: 146235-14-5
• Molecular Formula: C₃₅H₃₆O₆
• Molecular Weight: 552.667
• Mol file: 146235-14-5.mol

Synonyms:benzyl 4,4¹-anhydro-2,3,6-tri-O-benzyl-4-C-hydroxymethyl-α-D-glucopyranoside

Chemical Property of benzyl 4,4¹-anhydro-2,3,6-tri-O-benzyl-4-C-hydroxymethyl-α-D-glucopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of benzyl 4,4¹-anhydro-2,3,6-tri-O-benzyl-4-C-hydroxymethyl-α-D-glucopyranoside

There total 1 articles about benzyl 4,4¹-anhydro-2,3,6-tri-O-benzyl-4-C-hydroxymethyl-α-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

benzyl 2,3,6-tri-O-benzyl-4-deoxy-4-C-(methylene)-α-D-xylo-4-hexopyranoside (125219-21-8) → benzyl 4,41-anhydro-2,3,6-tri-O-benzyl-4-C-hydroxymethyl-α-D-galactopyranoside (141250-12-6) + benzyl 4,41-anhydro-2,3,6-tri-O-benzyl-4-C-hydroxymethyl-α-D-glucopyranoside (146235-14-5)

Guidance literature:

With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; for 16h; Yield given. Yields of byproduct given; Ambient temperature;

DOI:10.1016/0008-6215(92)80085-F

Reference yield: 80.0%

benzyl 4,41-anhydro-2,3,6-tri-O-benzyl-4-C-hydroxymethyl-α-D-glucopyranoside (146235-14-5) → Benzyl 2,3,6-Tri-O-benzyl-4-C-(methyl)-α-D-glucopyranoside (139070-97-6)

Guidance literature:

With hydrogen; Lindlar's catalyst; In methanol; ethyl acetate; for 16h;

DOI:10.1016/0008-6215(92)80085-F

upstream raw materials:

benzyl 2,3,6-tri-O-benzyl-4-deoxy-4-C-(methylene)-α-D-xylo-4-hexopyranoside

Downstream raw materials:

Benzyl 2,3,6-Tri-O-benzyl-4-C-(methyl)-α-D-glucopyranoside