tert-butyl (Z)-2-(2-isocyanophenyl)-1-phenylethenyl carbonate

Base Information

• Chemical Name: tert-butyl (Z)-2-(2-isocyanophenyl)-1-phenylethenyl carbonate
• CAS No.: 1433999-61-1
• Molecular Formula: C₂₀H₁₉NO₃
• Molecular Weight: 321.376
• Mol file: 1433999-61-1.mol

Synonyms:tert-butyl (Z)-2-(2-isocyanophenyl)-1-phenylethenyl carbonate

Chemical Property of tert-butyl (Z)-2-(2-isocyanophenyl)-1-phenylethenyl carbonate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of tert-butyl (Z)-2-(2-isocyanophenyl)-1-phenylethenyl carbonate

There total 1 articles about tert-butyl (Z)-2-(2-isocyanophenyl)-1-phenylethenyl carbonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

di-tert-butyl dicarbonate (24424-99-5) + 2-(2-isocyanophenyl)-1-phenylethanone (69622-49-7) → tert-butyl (Z)-2-(2-isocyanophenyl)-1-phenylethenyl carbonate (1433999-61-1)

Guidance literature:

With pyridine; dmap; at 20 ℃;

DOI:10.1002/hlca.201200236

Reference yield: 82.0%

tert-butyl (Z)-2-(2-isocyanophenyl)-1-phenylethenyl carbonate (1433999-61-1) → tert-butyl (Z)-2-(2-isothiocyanatophenyl)-1-phenylethenyl carbonate (1433999-66-6)

Guidance literature:

With sulfur; selenium; triethylamine; In tetrahydrofuran; at 20 ℃;

DOI:10.1002/hlca.201200236

Reference yield:

tert-butyl (Z)-2-(2-isocyanophenyl)-1-phenylethenyl carbonate (1433999-61-1) → C24H28N2O3S

Guidance literature:

Multi-step reaction with 2 steps

1: sulfur; selenium; triethylamine / tetrahydrofuran / 20 °C

2: dichloromethane / 20 °C

With sulfur; selenium; triethylamine; In tetrahydrofuran; dichloromethane;

DOI:10.1002/hlca.201200236

upstream raw materials:

di-tert-butyl dicarbonate

2-(2-isocyanophenyl)-1-phenylethanone

Downstream raw materials:

tert-butyl (Z)-2-(2-isothiocyanatophenyl)-1-phenylethenyl carbonate

(2-phenyl-1H-indol-1-yl)(pyrrolidin-1-yl)methanethione

(2-phenyl-1H-indol-1-yl)(piperidin-1-yl)methanethione