triisopropyl-{1-[2-(4-methoxy-phenoxy)-ethyl]-1-methyl-but-2-enyloxy}-silane

Base Information

Chemical Name:triisopropyl-{1-[2-(4-methoxy-phenoxy)-ethyl]-1-methyl-but-2-enyloxy}-silane
CAS No.:904834-14-6
Molecular Formula:C₂₃H₄₀O₃Si
Molecular Weight:392.654
Hs Code.:

Synonyms:triisopropyl-{1-[2-(4-methoxy-phenoxy)-ethyl]-1-methyl-but-2-enyloxy}-silane

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Chemical Property of triisopropyl-{1-[2-(4-methoxy-phenoxy)-ethyl]-1-methyl-but-2-enyloxy}-silane

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Technology Process of triisopropyl-{1-[2-(4-methoxy-phenoxy)-ethyl]-1-methyl-but-2-enyloxy}-silane

There total 7 articles about triisopropyl-{1-[2-(4-methoxy-phenoxy)-ethyl]-1-methyl-but-2-enyloxy}-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 904833-30-3
4-(4-methoxy-phenoxy)-2-methyl-2-triisopropylsilanyloxy-butyraldehyde

: 1530-32-1
ethyltriphenylphosphonium bromide

: 904834-14-6
triisopropyl-{1-[2-(4-methoxy-phenoxy)-ethyl]-1-methyl-but-2-enyloxy}-silane

Guidance literature:: With n-butyllithium; In tetrahydrofuran; at -10 ℃; for 3h;
DOI:10.1055/s-2006-932487

Reference yield:

: 904834-06-6
2,2-dimethyl-propionic acid 2-hydroxy-4-(4-methoxy-phenoxy)-2-methyl-butyl ester

: 904834-14-6
triisopropyl-{1-[2-(4-methoxy-phenoxy)-ethyl]-1-methyl-but-2-enyloxy}-silane

Guidance literature:: Multi-step reaction with 4 steps

1: 2,6-lutidine / CH₂Cl₂ / 24 h / 20 °C

2: DIBAL-H / toluene / 2 h / -78 - 0 °C

3: 89 percent / (COCl)2; DMSO; Et₃N / CH₂Cl₂ / -78 - -20 °C

4: 89 percent / n-BuLi / tetrahydrofuran / 3 h / -10 °C

With 2,6-dimethylpyridine; n-butyllithium; oxalyl dichloride; diisobutylaluminium hydride; dimethyl sulfoxide; triethylamine; In tetrahydrofuran; dichloromethane; toluene; 3: Swern oxidation / 4: Wittig olefination;
DOI:10.1055/s-2006-932487

Reference yield:

: 904833-22-3
4-(4-methoxy-phenoxy)-2-methyl-2-triisopropylsilanyloxy-butan-1-ol

: 904834-14-6
triisopropyl-{1-[2-(4-methoxy-phenoxy)-ethyl]-1-methyl-but-2-enyloxy}-silane

Guidance literature:: Multi-step reaction with 2 steps

1: 89 percent / (COCl)2; DMSO; Et₃N / CH₂Cl₂ / -78 - -20 °C

2: 89 percent / n-BuLi / tetrahydrofuran / 3 h / -10 °C

With n-butyllithium; oxalyl dichloride; dimethyl sulfoxide; triethylamine; In tetrahydrofuran; dichloromethane; 1: Swern oxidation / 2: Wittig olefination;
DOI:10.1055/s-2006-932487