4-Bromo-1-methoxy-2-(2-nitrovinyl)benzene

Base Information

Chemical Name:4-Bromo-1-methoxy-2-(2-nitrovinyl)benzene
CAS No.:175205-14-8
Molecular Formula:C9H8 Br N O3
Molecular Weight:258.06900
Hs Code.:
European Community (EC) Number:681-387-9
Nikkaji Number:J3.055.434E
NSC Number:278623
Wikidata:Q106902800
Mol file:175205-14-8.mol

Synonyms:175205-14-8;4-bromo-1-methoxy-2-(2-nitrovinyl)benzene;(E)-4-bromo-1-methoxy-2-(2-nitrovinyl)benzene;1380095-40-8;5-Bromo-2-methoxy-omega-nitrostyrene;4-bromo-1-methoxy-2-[(E)-2-nitroethenyl]benzene;NSC278623;SCHEMBL8639564;HMS561H21;AKOS008967958;NSC-278623;?5-BROMO-2-METHOXY-OMEGA-NITROSTYRENE;Benzene,4-bromo-1-methoxy-2-(2-nitroethenyl)-;EN300-1911982

Suppliers and Price of 4-Bromo-1-methoxy-2-(2-nitrovinyl)benzene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

American Custom Chemicals Corporation
4-BROMO-1-METHOXY-2-(2-NITROVINYL)BENZENE 95.00%
5G
$ 1086.62

American Custom Chemicals Corporation
4-BROMO-1-METHOXY-2-(2-NITROVINYL)BENZENE 95.00%
1G
$ 691.27

Alfa Aesar
5-Bromo-2-methoxy-beta-nitrostyrene, 97%
5g
$ 167.00

Alfa Aesar
5-Bromo-2-methoxy-beta-nitrostyrene, 97%
1g
$ 47.80

Total 6 raw suppliers

Chemical Property of 4-Bromo-1-methoxy-2-(2-nitrovinyl)benzene

Chemical Property:

Vapor Pressure:5.61E-05mmHg at 25°C
Melting Point:120-122oC
Boiling Point:357.5oC at 760 mmHg
Flash Point:170oC
PSA：55.05000
Density:1.546g/cm3
LogP:3.22830
XLogP3:2.8
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:2
Exact Mass:256.96876
Heavy Atom Count:14
Complexity:227

Purity/Quality:

98%Min ^*data from raw suppliers

4-BROMO-1-METHOXY-2-(2-NITROVINYL)BENZENE 95.00% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:
Statements: 20/21/22-36/37/38
Safety Statements: 26-36/37/39

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COC1=C(C=C(C=C1)Br)C=C[N+](=O)[O-]
Isomeric SMILES:COC1=C(C=C(C=C1)Br)/C=C/[N+](=O)[O-]

Technology Process of 4-Bromo-1-methoxy-2-(2-nitrovinyl)benzene

There total 1 articles about 4-Bromo-1-methoxy-2-(2-nitrovinyl)benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 75-52-5
nitromethane

: 25016-01-7
5-bromo-2-methoxybenzaldehyde

: 175205-14-8
4-Bromo-1-methoxy-2-((E)-2-nitro-vinyl)-benzene

Guidance literature:: With ammonium acetate; for 4h; Heating;
DOI:10.1021/jm0100739

Reference yield: 83.0%

: 5633-34-1
(benzoylmethylene)dimethylsulfurane

: 175205-14-8
4-Bromo-1-methoxy-2-((E)-2-nitro-vinyl)-benzene

: 1380095-16-8
(4R,5S)-5-benzoyl-4-(5-bromo-2-methoxyphenyl)oxazolidin-2-one

: (4S,5R)-5-Benzoyl-4-(5-bromo-2-methoxyphenyl)oxazolidin-2-one

Guidance literature:: 4-Bromo-1-methoxy-2-((E)-2-nitro-vinyl)-benzene; With dmap; 1,1'-((1R,2R)-1,2-diphenylethane-1,2-diyl)bis(3-(3,5-bis(trifluoromethyl)phenyl)urea); o-chlorophenylthiourea; In 5,5-dimethyl-1,3-cyclohexadiene; at -35 ℃; for 0.5h;

(benzoylmethylene)dimethylsulfurane; In 5,5-dimethyl-1,3-cyclohexadiene; at -35 - 35 ℃; for 120h; optical yield given as %ee; enantioselective reaction;
DOI:10.1002/chem.201104021