2-((4S,5S)-5-((benzyloxy)methyl)-2,2-dimethyl-1,3-dioxolan-4-yl)acetaldehyde

Base Information

Chemical Name:2-((4S,5S)-5-((benzyloxy)methyl)-2,2-dimethyl-1,3-dioxolan-4-yl)acetaldehyde
CAS No.:562823-58-9
Molecular Formula:C₁₅H₂₀O₄
Molecular Weight:264.321
Hs Code.:

Synonyms:2-((4S,5S)-5-((benzyloxy)methyl)-2,2-dimethyl-1,3-dioxolan-4-yl)acetaldehyde

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 2-((4S,5S)-5-((benzyloxy)methyl)-2,2-dimethyl-1,3-dioxolan-4-yl)acetaldehyde

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Technology Process of 2-((4S,5S)-5-((benzyloxy)methyl)-2,2-dimethyl-1,3-dioxolan-4-yl)acetaldehyde

There total 15 articles about 2-((4S,5S)-5-((benzyloxy)methyl)-2,2-dimethyl-1,3-dioxolan-4-yl)acetaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: C₁₆H₂₂O₄

: 562823-58-9
2-((4S,5S)-5-((benzyloxy)methyl)-2,2-dimethyl-1,3-dioxolan-4-yl)acetaldehyde

Guidance literature:: With mercury(II) diacetate; In tetrahydrofuran; water; at 0 - 20 ℃;
DOI:10.1039/c6ob01447j

Reference yield: 87.0%

: 562823-71-6
2-((4S,5S)-5-(benzyloxymethyl)-2,2-dimethyl-1,3-dioxolan-4-yl)ethanol

: 562823-58-9
2-((4S,5S)-5-((benzyloxy)methyl)-2,2-dimethyl-1,3-dioxolan-4-yl)acetaldehyde

Guidance literature:: With sodium hydrogencarbonate; Dess-Martin periodane; In dichloromethane; at 23 ℃; for 2h;
DOI:10.1016/S0040-4039(03)00744-5

Reference yield:

: 127665-77-4
(E)-5-(2,2-dimethyl-1,1-diphenyl-1-silapropoxy)pent-2-en-1-ol

: 562823-58-9
2-((4S,5S)-5-((benzyloxy)methyl)-2,2-dimethyl-1,3-dioxolan-4-yl)acetaldehyde

Guidance literature:: Multi-step reaction with 5 steps

1.1: NaH / tetrahydrofuran / 0.5 h

1.2: tetrabutylammonium iodide / tetrahydrofuran

2.1: 2.8 g / AD-mix α; methanesulfonamide; H2O / 2-methyl-propan-2-ol / 0 °C

3.1: 93 percent / p-toluenesulfonic acid monohydrate

4.1: TBAF / tetrahydrofuran

5.1: CrO₃ / acetone / 0 °C

With chromium(VI) oxide; AD-mix-α; methanesulfonamide; tetrabutyl ammonium fluoride; water; sodium hydride; toluene-4-sulfonic acid; In tetrahydrofuran; acetone; tert-butyl alcohol; 2.1: Sharpless asymmetric dihydroxylation;
DOI:10.1021/jm034216y