(2S,4aR,6S,7R,8S,8aR)-6-Methoxy-7,8-bis-methoxymethoxy-2-(4-methoxy-phenyl)-hexahydro-pyrano[3,2-d][1,3]dioxine

Base Information

Chemical Name:(2S,4aR,6S,7R,8S,8aR)-6-Methoxy-7,8-bis-methoxymethoxy-2-(4-methoxy-phenyl)-hexahydro-pyrano[3,2-d][1,3]dioxine
CAS No.:845643-97-2
Molecular Formula:C₁₉H₂₈O₉
Molecular Weight:400.426
Hs Code.:

Synonyms:(2S,4aR,6S,7R,8S,8aR)-6-Methoxy-7,8-bis-methoxymethoxy-2-(4-methoxy-phenyl)-hexahydro-pyrano[3,2-d][1,3]dioxine

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Chemical Property of (2S,4aR,6S,7R,8S,8aR)-6-Methoxy-7,8-bis-methoxymethoxy-2-(4-methoxy-phenyl)-hexahydro-pyrano[3,2-d][1,3]dioxine

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Technology Process of (2S,4aR,6S,7R,8S,8aR)-6-Methoxy-7,8-bis-methoxymethoxy-2-(4-methoxy-phenyl)-hexahydro-pyrano[3,2-d][1,3]dioxine

There total 3 articles about (2S,4aR,6S,7R,8S,8aR)-6-Methoxy-7,8-bis-methoxymethoxy-2-(4-methoxy-phenyl)-hexahydro-pyrano[3,2-d][1,3]dioxine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: 107-30-2
chloromethyl methyl ether

: 161443-22-7
methyl 4,6-O-(4-methoxybenzylidene)-α-D-glucopyranoside

: 845643-97-2
(2S,4aR,6S,7R,8S,8aR)-6-Methoxy-7,8-bis-methoxymethoxy-2-(4-methoxy-phenyl)-hexahydro-pyrano[3,2-d][1,3]dioxine

Guidance literature:: With N-ethyl-N,N-diisopropylamine; In dichloromethane; at 20 ℃; for 53h;
DOI:10.1021/ol0477374

Reference yield:

: 2186-92-7
p-Anisaldehyde dimethyl acetal

: 845643-97-2
(2S,4aR,6S,7R,8S,8aR)-6-Methoxy-7,8-bis-methoxymethoxy-2-(4-methoxy-phenyl)-hexahydro-pyrano[3,2-d][1,3]dioxine

Guidance literature:: Multi-step reaction with 2 steps

1: 92 percent / Amberlyst 15 / dimethylformamide / 21 h / 80 °C

2: 83 percent / i-Pr₂NEt / CH₂Cl₂ / 53 h / 20 °C

With Amberlyst 15; N-ethyl-N,N-diisopropylamine; In dichloromethane; N,N-dimethyl-formamide;
DOI:10.1021/ol0477374

Reference yield:

: 97-30-3
methyl-alpha-D-glucopyranoside

: 845643-97-2
(2S,4aR,6S,7R,8S,8aR)-6-Methoxy-7,8-bis-methoxymethoxy-2-(4-methoxy-phenyl)-hexahydro-pyrano[3,2-d][1,3]dioxine

Guidance literature:: Multi-step reaction with 2 steps

1: 92 percent / Amberlyst 15 / dimethylformamide / 21 h / 80 °C

2: 83 percent / i-Pr₂NEt / CH₂Cl₂ / 53 h / 20 °C

With Amberlyst 15; N-ethyl-N,N-diisopropylamine; In dichloromethane; N,N-dimethyl-formamide;
DOI:10.1021/ol0477374