C₃₂H₄₆O₃Si

Base Information

• Chemical Name: C₃₂H₄₆O₃Si
• CAS No.: 1362110-27-7
• Molecular Formula: C₃₂H₄₆O₃Si
• Molecular Weight: 506.801
• Mol file: 1362110-27-7.mol

Synonyms:C₃₂H₄₆O₃Si

Chemical Property of C₃₂H₄₆O₃Si

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₃₂H₄₆O₃Si

There total 3 articles about C₃₂H₄₆O₃Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C32H48O4Si → C32H46O3Si (1362110-27-7)

Guidance literature:

With Burgess Reagent; In tetrahydrofuran; at 20 - 50 ℃; Inert atmosphere;

DOI:10.1021/ol300390k

Reference yield:

C32H47IO4Si (1362110-25-5) → C32H46O3Si (1362110-27-7)

Guidance literature:

Multi-step reaction with 2 steps

1.1: tert.-butyl lithium / tetrahydrofuran / 0.17 h / -78 °C / Inert atmosphere

1.2: brine

2.1: Burgess Reagent / tetrahydrofuran / 20 - 50 °C / Inert atmosphere

With Burgess Reagent; tert.-butyl lithium; In tetrahydrofuran; 1.1: Barbier type cyclization;

DOI:10.1021/ol300390k

Reference yield:

C32H48O5Si → C32H46O3Si (1362110-27-7)

Guidance literature:

Multi-step reaction with 3 steps

1.1: 1H-imidazole; iodine; triphenylphosphine / tetrahydrofuran / 0.17 h / 0 - 20 °C / Inert atmosphere

2.1: tert.-butyl lithium / tetrahydrofuran / 0.17 h / -78 °C / Inert atmosphere

2.2: brine

3.1: Burgess Reagent / tetrahydrofuran / 20 - 50 °C / Inert atmosphere

With 1H-imidazole; Burgess Reagent; iodine; tert.-butyl lithium; triphenylphosphine; In tetrahydrofuran; 2.1: Barbier type cyclization;

DOI:10.1021/ol300390k

upstream raw materials:

C₃₂H₄₇IO₄Si

Downstream raw materials:

C₃₂H₄₆O₅Si

C₃₄H₅₀O₆Si

C₂₅H₃₀O₆

C₂₅H₂₉IO₆

Refernces