[chlororuthenium(II)(cis-1,2-bis(diphenylphosphino)ethylene)(4'-(4-tolyl)-2,2':6',2''-terpyridine)]chloride

Base Information

Chemical Name:[chlororuthenium(II)(cis-1,2-bis(diphenylphosphino)ethylene)(4'-(4-tolyl)-2,2':6',2''-terpyridine)]chloride
CAS No.:932368-67-7
Molecular Formula:C₄₈H₃₉ClN₃P₂Ru*Cl
Molecular Weight:891.781
Hs Code.:

Synonyms:[chlororuthenium(II)(cis-1,2-bis(diphenylphosphino)ethylene)(4'-(4-tolyl)-2,2':6',2''-terpyridine)]chloride

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Chemical Property of [chlororuthenium(II)(cis-1,2-bis(diphenylphosphino)ethylene)(4'-(4-tolyl)-2,2':6',2''-terpyridine)]chloride

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Technology Process of [chlororuthenium(II)(cis-1,2-bis(diphenylphosphino)ethylene)(4'-(4-tolyl)-2,2':6',2''-terpyridine)]chloride

There total 1 articles about [chlororuthenium(II)(cis-1,2-bis(diphenylphosphino)ethylene)(4'-(4-tolyl)-2,2':6',2''-terpyridine)]chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 136276-24-9
[trichloro(4'-tolyl-2,2':6',2''-terpyridine)ruthenium(III)]

: 983-80-2
cis-1,2-bis-(diphenylphosphino)ethene

: 932368-67-7
[chlororuthenium(II)(cis-1,2-bis(diphenylphosphino)ethylene)(4'-(4-tolyl)-2,2':6',2''-terpyridine)]chloride

Guidance literature:: With triethylamine; lithium chloride; In ethanol; dichloromethane; (N2), Ru complex (0.38 mmol) and ligand (0.45 mmol) refluxed in CH2Cl2/EtOH (3:1) in the presence of Et3N and LiCl for 3 h; filtered, evapd., recrystd.(acetone), pptd.(Et2O), elem. anal.;
DOI:10.1016/j.molcata.2006.05.059

Reference yield: 65.0%

: ammonium hexafluorophosphate

: 932368-67-7
[chlororuthenium(II)(cis-1,2-bis(diphenylphosphino)ethylene)(4'-(4-tolyl)-2,2':6',2''-terpyridine)]chloride

: 7732-18-5
water

: [(aqua)ruthenium(II)(cis-1,2-bis(diphenylphosphino)ethylene)(4'-(4-tolyl)-2,2':6',2''-terpyridine)] hexafluorophosphate

Guidance literature:: With silver(I) 4-methylbenzenesulfonate; In ethanol; water; byproducts: AgCl; (N2), Ru complex (0.11 mmol) and silver p-toluenesulfonate (0.26 mmol) refluxed in EtOH/H2O (1:1) for 5 h, hot filtered, pptd.(satd. aq. NH4PF6); concd., pptd., filtered, washed (cold H2O, Et2O), dried (vac.), repptd.(acetone/Et2O), elem. anal.;
DOI:10.1016/j.molcata.2006.05.059