phenyltitanium(III) tetraphenylporphyrin

Base Information

• Chemical Name: phenyltitanium(III) tetraphenylporphyrin
• CAS No.: 74506-95-9
• Molecular Formula: C₅₀H₃₃N₄Ti
• Molecular Weight: 737.719
• Mol file: 74506-95-9.mol

Synonyms:phenyltitanium(III) tetraphenylporphyrin

Chemical Property of phenyltitanium(III) tetraphenylporphyrin

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of phenyltitanium(III) tetraphenylporphyrin

There total 1 articles about phenyltitanium(III) tetraphenylporphyrin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

fluoro(tetraphenylporphyrinato)titanium(III) (71454-15-4) → phenyltitanium(III) tetraphenylporphyrin (74506-95-9)

Guidance literature:

With phenylmagnesium bromide; In tetrahydrofuran; toluene; byproducts: MgBrF; (Ar); Ti complex was treated with Grignard reagent according to J. H. Teuben and H. J. De Liefde Meijer, J. Organometal. Chem., 46(1972) 313; react. was monitored by ESR;

DOI:10.1016/S0022-328X(00)83990-X

Reference yield:

phenyltitanium(III) tetraphenylporphyrin (74506-95-9) → biphenyl (92-52-4,1594-86-1) + oxotitanium(IV) meso-tetraphenylporphinato (58384-89-7)

Guidance literature:

With oxygen; In toluene; react. of soln. of Ti complex with O2; biphenyl was sepd. by TLC and identified by IR;

DOI:10.1016/S0022-328X(00)83990-X

upstream raw materials:

fluoro(tetraphenylporphyrinato)titanium(III)

Downstream raw materials:

biphenyl

oxotitanium(IV) meso-tetraphenylporphinato