3-[3-(tert-butyldimethylsiloxy)propyl]-6-(tert-butyldiphenylsiloxy)hex-2-enyl Vinyl Ether

Base Information

Chemical Name:3-[3-(tert-butyldimethylsiloxy)propyl]-6-(tert-butyldiphenylsiloxy)hex-2-enyl Vinyl Ether
CAS No.:503000-30-4
Molecular Formula:C₃₃H₅₂O₃Si₂
Molecular Weight:552.945
Hs Code.:

Synonyms:3-[3-(tert-butyldimethylsiloxy)propyl]-6-(tert-butyldiphenylsiloxy)hex-2-enyl Vinyl Ether

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Chemical Property of 3-[3-(tert-butyldimethylsiloxy)propyl]-6-(tert-butyldiphenylsiloxy)hex-2-enyl Vinyl Ether

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Technology Process of 3-[3-(tert-butyldimethylsiloxy)propyl]-6-(tert-butyldiphenylsiloxy)hex-2-enyl Vinyl Ether

There total 4 articles about 3-[3-(tert-butyldimethylsiloxy)propyl]-6-(tert-butyldiphenylsiloxy)hex-2-enyl Vinyl Ether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: 109-92-2,25104-37-4
ethyl vinyl ether

: 503000-46-2
3-[3-(tert-butyl-dimethyl-silanyloxy)-propyl]-6-(tert-butyl-diphenyl-silanyloxy)-hex-2-en-1-ol

: 503000-30-4
3-[3-(tert-butyldimethylsiloxy)propyl]-6-(tert-butyldiphenylsiloxy)hex-2-enyl Vinyl Ether

Guidance literature:: With mercury(II) diacetate; for 24h; Heating;
DOI:10.1021/ol034020s

Reference yield:

: 215251-69-7
4-(tert-butyldiphenylsilyloxy)-N-methoxy-N-methylbutanamide

: 503000-30-4
3-[3-(tert-butyldimethylsiloxy)propyl]-6-(tert-butyldiphenylsiloxy)hex-2-enyl Vinyl Ether

Guidance literature:: Multi-step reaction with 4 steps

1: 63 percent / t-BuLi / tetrahydrofuran; pentane / -78 - 20 °C

2: 96 percent / NaH / 1,2-dimethoxy-ethane; various solvent(s) / 6 h / Heating

3: 99 percent / DIBAL-H / tetrahydrofuran; hexane / 0.5 h / 0 °C

4: 81 percent / Hg(OAc)2 / 24 h / Heating

With mercury(II) diacetate; tert.-butyl lithium; sodium hydride; diisobutylaluminium hydride; In tetrahydrofuran; 1,2-dimethoxyethane; hexane; pentane; 2: Horner-Emmons reaction;
DOI:10.1021/ol034020s

Reference yield:

: 503000-45-1
1-(tert-butyl-dimethyl-silanyloxy)-7-(tert-butyl-diphenyl-silanyloxy)-heptan-4-one

: 503000-30-4
3-[3-(tert-butyldimethylsiloxy)propyl]-6-(tert-butyldiphenylsiloxy)hex-2-enyl Vinyl Ether

Guidance literature:: Multi-step reaction with 3 steps

1: 96 percent / NaH / 1,2-dimethoxy-ethane; various solvent(s) / 6 h / Heating

2: 99 percent / DIBAL-H / tetrahydrofuran; hexane / 0.5 h / 0 °C

3: 81 percent / Hg(OAc)2 / 24 h / Heating

With mercury(II) diacetate; sodium hydride; diisobutylaluminium hydride; In tetrahydrofuran; 1,2-dimethoxyethane; hexane; 1: Horner-Emmons reaction;
DOI:10.1021/ol034020s