methyl-4-O-benzyl-6-C-(n-butyl)-2,3,6-trideoxy-α-D-erythro-hexopyranoside

Base Information

Chemical Name:methyl-4-O-benzyl-6-C-(n-butyl)-2,3,6-trideoxy-α-D-erythro-hexopyranoside
CAS No.:93105-94-3
Molecular Formula:C₁₈H₂₈O₃
Molecular Weight:292.419
Hs Code.:

Synonyms:methyl-4-O-benzyl-6-C-(n-butyl)-2,3,6-trideoxy-α-D-erythro-hexopyranoside

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of methyl-4-O-benzyl-6-C-(n-butyl)-2,3,6-trideoxy-α-D-erythro-hexopyranoside

Chemical Property:

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Technology Process of methyl-4-O-benzyl-6-C-(n-butyl)-2,3,6-trideoxy-α-D-erythro-hexopyranoside

There total 9 articles about methyl-4-O-benzyl-6-C-(n-butyl)-2,3,6-trideoxy-α-D-erythro-hexopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

: 93105-93-2,93126-13-7
methyl-4-O-benzyl-6-C-(n-butylidene)-2,3,6-trideoxy-α-D-erythro-hexopyranoside

: 93105-94-3
methyl-4-O-benzyl-6-C-(n-butyl)-2,3,6-trideoxy-α-D-erythro-hexopyranoside

Guidance literature:: With hydrogen; nickel; In methanol; for 3h; Ambient temperature;
DOI:10.1016/S0040-4020(01)91120-2

Reference yield:

: 64526-50-7
methyl-4-O-benzyl-2,3-dideoxy-α-D-erythro-hexopyranoside

: 93105-94-3
methyl-4-O-benzyl-6-C-(n-butyl)-2,3,6-trideoxy-α-D-erythro-hexopyranoside

Guidance literature:: Multi-step reaction with 3 steps

1: 1 g / 1) oxalyl chloride, dimethyl sulfoxide; 2) Et₃N / CH₂Cl₂ / -78 °C / 1) 15 min; 2) 15 min

2: n-BuLi / toluene; hexane / -78 - 20 °C

3: 69 percent / H₂ / Raney Ni / methanol / 3 h / Ambient temperature

With n-butyllithium; oxalyl dichloride; hydrogen; dimethyl sulfoxide; triethylamine; nickel; In methanol; hexane; dichloromethane; toluene;
DOI:10.1016/S0040-4020(01)91120-2

Reference yield:

: 23339-18-6
methyl 2,3-dideoxy-α,β-D-erythro-hexopyranoside

: 93105-94-3
methyl-4-O-benzyl-6-C-(n-butyl)-2,3,6-trideoxy-α-D-erythro-hexopyranoside

Guidance literature:: Multi-step reaction with 6 steps

1: 29.4 g / pyridine / Ambient temperature

2: 36 g / KH / tetrahydrofuran / 0 - 20 °C

3: 2 eq. tetrabutylammonium fluoride / tetrahydrofuran / 4 h / Ambient temperature

4: 1 g / 1) oxalyl chloride, dimethyl sulfoxide; 2) Et₃N / CH₂Cl₂ / -78 °C / 1) 15 min; 2) 15 min

5: n-BuLi / toluene; hexane / -78 - 20 °C

6: 69 percent / H₂ / Raney Ni / methanol / 3 h / Ambient temperature

With pyridine; n-butyllithium; oxalyl dichloride; tetrabutyl ammonium fluoride; hydrogen; potassium hydride; dimethyl sulfoxide; triethylamine; nickel; In tetrahydrofuran; methanol; hexane; dichloromethane; toluene;
DOI:10.1016/S0040-4020(01)91120-2