(2-hydroxyl-2-phenyl-1-trimethylsilyl-3(Z)-buten-4-yl)(pyridine)bis(dimethylglyoximato)cobalt(III)

Base Information

• Chemical Name: (2-hydroxyl-2-phenyl-1-trimethylsilyl-3(Z)-buten-4-yl)(pyridine)bis(dimethylglyoximato)cobalt(III)
• CAS No.: 287120-54-1
• Molecular Formula: C₂₆H₃₈CoN₅O₅Si
• Molecular Weight: 587.697

Synonyms:(2-hydroxyl-2-phenyl-1-trimethylsilyl-3(Z)-buten-4-yl)(pyridine)bis(dimethylglyoximato)cobalt(III)

Chemical Property of (2-hydroxyl-2-phenyl-1-trimethylsilyl-3(Z)-buten-4-yl)(pyridine)bis(dimethylglyoximato)cobalt(III)

Chemical Property:

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Technology Process of (2-hydroxyl-2-phenyl-1-trimethylsilyl-3(Z)-buten-4-yl)(pyridine)bis(dimethylglyoximato)cobalt(III)

There total 3 articles about (2-hydroxyl-2-phenyl-1-trimethylsilyl-3(Z)-buten-4-yl)(pyridine)bis(dimethylglyoximato)cobalt(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

LiCH2SiMe3 + (1-phenyl-1-oxo-2(Z)-propen-3-yl)(pyridine)bis(dimethylglyoximato)cobalt(III) (25153-21-3,287200-31-1) + water (7732-18-5) → (2-hydroxyl-2-phenyl-1-trimethylsilyl-3(Z)-buten-4-yl)(pyridine)bis(dimethylglyoximato)cobalt(III) (287120-54-1)

Guidance literature:

With NH₄Cl; In tetrahydrofuran; under N2, the complex was dissolved in THF, the mixt. was cooled to 0°C, (trimethylsilyl methyl)lithium was slowly added by syringe, thesoln. was warmed to 25°C overnight and poured into an ice/satd. NH4Cl soln.; the mixt. was extd. with CH3CH2OCOCH3, dried (MgSO4), concd. (vac.);

DOI:10.1021/om000230m

Reference yield:

phenyl propargyl ketone (3623-15-2) → (2-hydroxyl-2-phenyl-1-trimethylsilyl-3(Z)-buten-4-yl)(pyridine)bis(dimethylglyoximato)cobalt(III) (287120-54-1)

Guidance literature:

Multi-step reaction with 2 steps

1: NaBH₄; NaOH / methanol

2: NH₄Cl / tetrahydrofuran

With NaBH₄; NaOH; NH₄Cl; In tetrahydrofuran; methanol;

DOI:10.1021/om000230m

Reference yield:

chloropyridinecobaloxime(III) → (2-hydroxyl-2-phenyl-1-trimethylsilyl-3(Z)-buten-4-yl)(pyridine)bis(dimethylglyoximato)cobalt(III) (287120-54-1)

Guidance literature:

Multi-step reaction with 2 steps

1: NaBH₄; NaOH / methanol

2: NH₄Cl / tetrahydrofuran

With NaBH₄; NaOH; NH₄Cl; In tetrahydrofuran; methanol;

DOI:10.1021/om000230m

upstream raw materials:

(1-phenyl-1-oxo-2(Z)-propen-3-yl)(pyridine)bis(dimethylglyoximato)cobalt(III)

water

phenyl propargyl ketone

Downstream raw materials:

(2-phenyl-1,3(Z)-butadiene-4-yl)(pyridine)bis(dimethylglyoximato)cobalt(III)

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