[5,15-bis(3,5-di-tert-butylphenyl)-10-phenyl-20-[p-(trimethylsilylethynyl)phenylethynyl]porphynato]nickel(II)

Base Information

• Chemical Name: [5,15-bis(3,5-di-tert-butylphenyl)-10-phenyl-20-[p-(trimethylsilylethynyl)phenylethynyl]porphynato]nickel(II)
• CAS No.: 1244778-22-0
• Molecular Formula: C₆₇H₆₈N₄NiSi
• Molecular Weight: 1016.08
• Mol file: 1244778-22-0.mol

Synonyms:[5,15-bis(3,5-di-tert-butylphenyl)-10-phenyl-20-[p-(trimethylsilylethynyl)phenylethynyl]porphynato]nickel(II)

Chemical Property of [5,15-bis(3,5-di-tert-butylphenyl)-10-phenyl-20-[p-(trimethylsilylethynyl)phenylethynyl]porphynato]nickel(II)

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [5,15-bis(3,5-di-tert-butylphenyl)-10-phenyl-20-[p-(trimethylsilylethynyl)phenylethynyl]porphynato]nickel(II)

There total 1 articles about [5,15-bis(3,5-di-tert-butylphenyl)-10-phenyl-20-[p-(trimethylsilylethynyl)phenylethynyl]porphynato]nickel(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 48.0%

[Ni((3,5-di-tert-butylphenyl)2(Ph)(HCC)C20H8N4)] (952190-21-5) + (4-bromophenyl)(trimethylsilyl)acetylene (16116-78-2) → [5,15-bis(3,5-di-tert-butylphenyl)-10-phenyl-20-[p-(trimethylsilylethynyl)phenylethynyl]porphynato]nickel(II) (1244778-22-0)

Guidance literature:

With Pd₂(C₆H₅CHCHCOCHCHC₆H₅)3; P(C₆H₅)3; CuI; In triethylamine; toluene; (inert atm.); stirring degassed soln. of porphyrin deriv., bromobenzene deriv., palladium compd., phosphine deriv. and CuI in dry toluene and triethylamine at 40°C for 2 h; filtration through silica, chromy. (silica gel, light petroleum ether/CH2Cl2 (5:1)), NMR and MS;

DOI:10.1039/c003715j

Reference yield: 100.0%

[5,15-bis(3,5-di-tert-butylphenyl)-10-phenyl-20-[p-(trimethylsilylethynyl)phenylethynyl]porphynato]nickel(II) (1244778-22-0) → [5,15-bis(3,5-di-tert-butylphenyl)-10-phenyl-20-[p-ethynylphenylethynyl]porphynato]nickel(II) (1309441-76-6)

Guidance literature:

With tetrabutyl ammonium fluoride; In tetrahydrofuran; dichloromethane; at 20 ℃; for 0.25h; Inert atmosphere;

DOI:10.1039/c003715j

upstream raw materials:

[Ni((3,5-di-tert-butylphenyl)2(Ph)(HCC)C₂₀H₈N₄)]

(4-bromophenyl)(trimethylsilyl)acetylene

Downstream raw materials:

[5,15-bis(3,5-di-tert-butylphenyl)-10-phenyl-20-[p-ethynylphenylethynyl]porphynato]nickel(II)

Refernces