(E)-(2S,3S,4S)-3-<(methoxycarbonyl)methyl>-4-(α-methyl-m-nitrostyryl)-1,2-pyrrolidinedicarboxylate

Base Information

Chemical Name:(E)-(2S,3S,4S)-3-<(methoxycarbonyl)methyl>-4-(α-methyl-m-nitrostyryl)-1,2-pyrrolidinedicarboxylate
CAS No.:87682-52-8
Molecular Formula:C₂₁H₂₆N₂O₈
Molecular Weight:434.446
Hs Code.:

Synonyms:(E)-(2S,3S,4S)-3-<(methoxycarbonyl)methyl>-4-(α-methyl-m-nitrostyryl)-1,2-pyrrolidinedicarboxylate

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Chemical Property of (E)-(2S,3S,4S)-3-<(methoxycarbonyl)methyl>-4-(α-methyl-m-nitrostyryl)-1,2-pyrrolidinedicarboxylate

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Technology Process of (E)-(2S,3S,4S)-3-<(methoxycarbonyl)methyl>-4-(α-methyl-m-nitrostyryl)-1,2-pyrrolidinedicarboxylate

There total 3 articles about (E)-(2S,3S,4S)-3-<(methoxycarbonyl)methyl>-4-(α-methyl-m-nitrostyryl)-1,2-pyrrolidinedicarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 10.0%

: 99-09-2
3-nitro-aniline

: 87682-50-6
ethyl methyl (2S,3S,4S)-3-(carboxymethyl)-4-isopropenyl-1,2-pyrrolidinedicarboxylate

: 87682-51-7
(Z)-(2S,3S,4S)-3-<(methoxycarbonyl)methyl>-4-(α-methyl-m-nitrostyryl)-1,2-pyrrolidinedicarboxylate

: 87682-52-8
(E)-(2S,3S,4S)-3-<(methoxycarbonyl)methyl>-4-(α-methyl-m-nitrostyryl)-1,2-pyrrolidinedicarboxylate

Guidance literature:: With tert.-butylnitrite; palladium diacetate; In acetonitrile; at 25 - 60 ℃;
DOI:10.1021/jm00367a010

Reference yield:

: 487-79-6
(-)-kainic acid

: 87682-52-8
(E)-(2S,3S,4S)-3-<(methoxycarbonyl)methyl>-4-(α-methyl-m-nitrostyryl)-1,2-pyrrolidinedicarboxylate

Guidance literature:: Multi-step reaction with 3 steps

1: sodium bicarbonate / H₂O / 2 h / 25 °C

2: diethyl ether

3: 10 percent / palladium acetate, tert-butyl nitrite / acetonitrile / 25 - 60 °C

With tert.-butylnitrite; palladium diacetate; sodium hydrogencarbonate; In diethyl ether; water; acetonitrile;
DOI:10.1021/jm00367a010

Reference yield:

: 87682-49-3
N-ethoxycarbonylkainic acid

: 87682-52-8
(E)-(2S,3S,4S)-3-<(methoxycarbonyl)methyl>-4-(α-methyl-m-nitrostyryl)-1,2-pyrrolidinedicarboxylate

Guidance literature:: Multi-step reaction with 2 steps

1: diethyl ether

2: 10 percent / palladium acetate, tert-butyl nitrite / acetonitrile / 25 - 60 °C

With tert.-butylnitrite; palladium diacetate; In diethyl ether; acetonitrile;
DOI:10.1021/jm00367a010