5-{[(2S,3R,4R,5S,6R)-6-(tert-Butyl-diphenyl-silanyloxymethyl)-4,5-dihydroxy-2-methylsulfanyl-tetrahydro-pyran-3-ylamino]-methylene}-1,3-dimethyl-pyrimidine-2,4,6-trione

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Chemical Name:5-{[(2S,3R,4R,5S,6R)-6-(tert-Butyl-diphenyl-silanyloxymethyl)-4,5-dihydroxy-2-methylsulfanyl-tetrahydro-pyran-3-ylamino]-methylene}-1,3-dimethyl-pyrimidine-2,4,6-trione
CAS No.:350239-13-3
Molecular Formula:C₃₀H₃₉N₃O₇SSi
Molecular Weight:613.807
Hs Code.:

5-{[(2S,3R,4R,5S,6R)-6-(tert-Butyl-diphenyl-silanyloxymethyl)-4,5-dihydroxy-2-methylsulfanyl-tetrahydro-pyran-3-ylamino]-methylene}-1,3-dimethyl-pyrimidine-2,4,6-trione

Synonyms:5-{[(2S,3R,4R,5S,6R)-6-(tert-Butyl-diphenyl-silanyloxymethyl)-4,5-dihydroxy-2-methylsulfanyl-tetrahydro-pyran-3-ylamino]-methylene}-1,3-dimethyl-pyrimidine-2,4,6-trione

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Chemical Property of 5-{[(2S,3R,4R,5S,6R)-6-(tert-Butyl-diphenyl-silanyloxymethyl)-4,5-dihydroxy-2-methylsulfanyl-tetrahydro-pyran-3-ylamino]-methylene}-1,3-dimethyl-pyrimidine-2,4,6-trione

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Technology Process of 5-{[(2S,3R,4R,5S,6R)-6-(tert-Butyl-diphenyl-silanyloxymethyl)-4,5-dihydroxy-2-methylsulfanyl-tetrahydro-pyran-3-ylamino]-methylene}-1,3-dimethyl-pyrimidine-2,4,6-trione

There total 1 articles about 5-{[(2S,3R,4R,5S,6R)-6-(tert-Butyl-diphenyl-silanyloxymethyl)-4,5-dihydroxy-2-methylsulfanyl-tetrahydro-pyran-3-ylamino]-methylene}-1,3-dimethyl-pyrimidine-2,4,6-trione which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 58479-61-1
tert-butylchlorodiphenylsilane

: 282526-15-2
methyl 2-[amino-5'-methylene-1',3'-dimethypyrimidine-2,4,6-(1H,3H,5H)trione]-2-deoxy-1-thio-β-D-glucopyranoside

: 350239-13-3
5-{[(2S,3R,4R,5S,6R)-6-(tert-Butyl-diphenyl-silanyloxymethyl)-4,5-dihydroxy-2-methylsulfanyl-tetrahydro-pyran-3-ylamino]-methylene}-1,3-dimethyl-pyrimidine-2,4,6-trione

Guidance literature:: With dmap; In 1,2-dichloro-ethane;
DOI:10.1016/S0040-4039(01)00366-5

Reference yield:

: 350239-13-3
5-{[(2S,3R,4R,5S,6R)-6-(tert-Butyl-diphenyl-silanyloxymethyl)-4,5-dihydroxy-2-methylsulfanyl-tetrahydro-pyran-3-ylamino]-methylene}-1,3-dimethyl-pyrimidine-2,4,6-trione

: 659722-02-8
methyl 4,6-O-benzylidene-2-deoxy-2-[(1,3-dimethyl-2,4,6(1H,3H,5H)-trioxopyrimidin-5-ylidene)methylamino]-1-thio-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: 84 percent / tetrabutylammonium fluoride / tetrahydrofuran

2: 77 percent / p-toluene sulphonic acid / acetonitrile

With tetrabutyl ammonium fluoride; toluene-4-sulfonic acid; In tetrahydrofuran; acetonitrile;
DOI:10.1016/S0040-4039(01)00366-5

Reference yield:

: 350239-13-3
5-{[(2S,3R,4R,5S,6R)-6-(tert-Butyl-diphenyl-silanyloxymethyl)-4,5-dihydroxy-2-methylsulfanyl-tetrahydro-pyran-3-ylamino]-methylene}-1,3-dimethyl-pyrimidine-2,4,6-trione

: 282526-18-5
methyl 2-deoxy-2-[(1,3-dimethyl-2,4,6(1H,3H,5H)-trioxopyrimidin-5-ylidene)methylamino]-3-O-(4-methoxybenzyl)-1-thio-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 4 steps

1: 84 percent / tetrabutylammonium fluoride / tetrahydrofuran

2: 77 percent / p-toluene sulphonic acid / acetonitrile

3: 82 percent / NaH / dimethylformamide

4: 70 percent / p-toluene sulphonic acid / methanol; acetonitrile

With tetrabutyl ammonium fluoride; sodium hydride; toluene-4-sulfonic acid; In tetrahydrofuran; methanol; N,N-dimethyl-formamide; acetonitrile;
DOI:10.1016/S0040-4039(01)00366-5