(1'R)-3'-exo--2'-exo-bornyl (2S)-hydroxy-3-phenylpropionate

Base Information

• Chemical Name: (1'R)-3'-exo--2'-exo-bornyl (2S)-hydroxy-3-phenylpropionate
• CAS No.: 105961-39-5
• Molecular Formula: C₃₃H₃₉NO₅S
• Molecular Weight: 561.742
• Mol file: 105961-39-5.mol

Synonyms:(1'R)-3'-exo--2'-exo-bornyl (2S)-hydroxy-3-phenylpropionate

Chemical Property of (1'R)-3'-exo--2'-exo-bornyl (2S)-hydroxy-3-phenylpropionate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

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Technology Process of (1'R)-3'-exo--2'-exo-bornyl (2S)-hydroxy-3-phenylpropionate

There total 2 articles about (1'R)-3'-exo--2'-exo-bornyl (2S)-hydroxy-3-phenylpropionate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

(1'R)-3'-exo--2'-exo-bornyl 3-phenylpropionate (105961-38-4) → (1'R)-3'-exo--2'-exo-bornyl (2S)-hydroxy-3-phenylpropionate (105961-39-5)

Guidance literature:

With MoO₅*pyridine*HMPA; potassium hexamethylsilazane; iso-butanol; In tetrahydrofuran; at -78 - -52 ℃; for 0.666667h;

DOI:10.1002/hlca.19860690310

Reference yield:

(1'R)-3'-exo--2'-exo-bornyl 3-phenylpropionate (105961-38-4) → (1'R)-3'-exo--2'-exo-bornyl (2S)-hydroxy-3-phenylpropionate (105961-39-5) + (R)-2-Hydroxy-3-phenyl-propionic acid (1R,2S,3R,4S)-3-[benzenesulfonyl-(3,5-dimethyl-phenyl)-amino]-1,7,7-trimethyl-bicyclo[2.2.1]hept-2-yl ester

Guidance literature:

With MoO₅*pyridine*HMPA; potassium hexamethylsilazane; iso-butanol; In tetrahydrofuran; at -78 - -52 ℃; hydroxylation with various basis, reaction time and temperature;

DOI:10.1002/hlca.19860690310

Reference yield: 74.0%

(1'R)-3'-exo--2'-exo-bornyl (2S)-hydroxy-3-phenylpropionate (105961-39-5) → L-3-phenyllactic acid (20312-36-1)

Guidance literature:

With potassium hydroxide; water; In methanol; for 7h;

DOI:10.1002/hlca.19860690310

upstream raw materials:

(1'R)-3'-exo--2'-exo-bornyl 3-phenylpropionate

Downstream raw materials:

L-3-phenyllactic acid