di(yclohexyl)phosphine sulfide

Base Information

• Chemical Name: di(yclohexyl)phosphine sulfide
• CAS No.: 14610-03-8
• Molecular Formula: C₁₂H₂₃PS
• Molecular Weight: 230.354
• Mol file: 14610-03-8.mol

Synonyms:di(yclohexyl)phosphine sulfide

Chemical Property of di(yclohexyl)phosphine sulfide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of di(yclohexyl)phosphine sulfide

There total 2 articles about di(yclohexyl)phosphine sulfide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

dicyclohexylphosphane (829-84-5) → di(yclohexyl)phosphine sulfide (14610-03-8)

Guidance literature:

With sulfur; In chloroform; for 2h; Ambient temperature;

DOI:10.1021/jo951327z

Reference yield:

→ di(yclohexyl)phosphine sulfide (14610-03-8)

Guidance literature:

Dicyclohexylphosphin, Schwefel, 14percentig. wss. NH3, 50-55grad, 1h;

Reference yield: 88.0%

[(μ-dicyclohexylphosphido)(κ2P,O-μ-dicyclohexylphosphido oxide)bis(dicyclohexylphosphane)diplatinum(I)](Pt-Pt) + di(yclohexyl)phosphine sulfide (14610-03-8) → [(PHCy2)Pt(μ-PCy2)(κ2P,S-μ-P(S)Cy2)Pt(PHCy2)] (1025043-97-3)

Guidance literature:

In toluene; Pt complex was added to soln. P(S)Cy2 in toluene and stirred at 50°C for 3 h; solvent was removed in vacuo, residue was washed with MeOH and dried in vacuo; elem. anal.;

DOI:10.1021/ic800045u

upstream raw materials:

dicyclohexylphosphane

Downstream raw materials:

tetracyclohexyl-diphosphane-P,P'-disulfide

3-(Dicyclohexyl-phosphinothioyl)-propionic acid

(R)-2-Azido-3-(dicyclohexyl-phosphinothioyl)-propionic acid

(R)-2-tert-Butoxycarbonylamino-3-(dicyclohexyl-phosphinothioyl)-propionic acid methyl ester

Refernces

• 1、 Gilbertson, Scott R.,Wang, Xifang. "Synthesis of (dicyclohexylphosphino) serine, its incorporation into a dodecapeptide, and the coordination of rhodium". . p. 434 - 435. Retrieved 2007/10/02.