C₃₀H₃₉IO₆Si

Base Information

• Chemical Name: C₃₀H₃₉IO₆Si
• CAS No.: 1260148-54-6
• Molecular Formula: C₃₀H₃₉IO₆Si
• Molecular Weight: 650.626
• Mol file: 1260148-54-6.mol

Synonyms:C₃₀H₃₉IO₆Si

Chemical Property of C₃₀H₃₉IO₆Si

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₃₀H₃₉IO₆Si

There total 17 articles about C₃₀H₃₉IO₆Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

C30H41IO6Si (1260148-66-0) → C30H39IO6Si (1260148-54-6)

Guidance literature:

With 2,3-dicyano-5,6-dichloro-p-benzoquinone; In chloroform; at 65 ℃; for 24h; diastereoselective reaction; Inert atmosphere;

DOI:10.1021/ol102652t

Reference yield:

C7H12O3 (1141365-68-5) → C30H39IO6Si (1260148-54-6)

Guidance literature:

Multi-step reaction with 4 steps

1.1: 1H-imidazole / N,N-dimethyl-formamide / 20 °C / Inert atmosphere

2.1: N,N,N,N,-tetramethylethylenediamine; titanium tetrachloride; lead(II) chloride; zinc / tetrahydrofuran; dichloromethane / 20 °C / Inert atmosphere

3.1: tert-butylmagnesium chloride / 3 h / -78 - 20 °C / Inert atmosphere

3.2: 20 °C

4.1: 2,3-dicyano-5,6-dichloro-p-benzoquinone / chloroform / 24 h / 65 °C / Inert atmosphere

With 1H-imidazole; N,N,N,N,-tetramethylethylenediamine; tert-butylmagnesium chloride; titanium tetrachloride; 2,3-dicyano-5,6-dichloro-p-benzoquinone; lead(II) chloride; zinc; In tetrahydrofuran; dichloromethane; chloroform; N,N-dimethyl-formamide;

DOI:10.1021/ol102652t

Reference yield:

methyl 2-(3,5-bis(benzyloxy)-2-formylphenyl)acetate (1260148-61-5) → C30H39IO6Si (1260148-54-6)

Guidance literature:

Multi-step reaction with 5 steps

1.1: boron tribromide / dichloromethane / -78 - 20 °C / Inert atmosphere

1.2: 0 °C

2.1: Me₄N(ICl₂); sodium hydrogencarbonate / dichloromethane / 16 h / 0 °C / Inert atmosphere

3.1: sodium tetrahydroborate / tetrahydrofuran / 0.5 h / 0 °C / Inert atmosphere

3.2: 0 °C

4.1: tert-butylmagnesium chloride / 3 h / -78 - 20 °C / Inert atmosphere

4.2: 20 °C

5.1: 2,3-dicyano-5,6-dichloro-p-benzoquinone / chloroform / 24 h / 65 °C / Inert atmosphere

With sodium tetrahydroborate; Me₄N(ICl₂); tert-butylmagnesium chloride; boron tribromide; sodium hydrogencarbonate; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In tetrahydrofuran; dichloromethane; chloroform;

DOI:10.1021/ol102652t

upstream raw materials:

C₇H₁₂O₃

C₁₃H₂₆O₃Si

C₁₄H₂₈O₂Si

C₁₆H₁₃IO₄