9-Fluorenone-1-boronic acid

Base Information

Chemical Name:9-Fluorenone-1-boronic acid
CAS No.:194470-10-5
Molecular Formula:C13H9BO3
Molecular Weight:224.024
Hs Code.:2931900090
DSSTox Substance ID:DTXSID80400706
Nikkaji Number:J863.595A
Wikidata:Q82203724
Mol file:194470-10-5.mol

Synonyms:9-Fluorenone-1-boronic acid;194470-10-5;(9-oxofluoren-1-yl)boronic Acid;(9-OXO-9H-FLUOREN-1-YL)BORONIC ACID;SCHEMBL8849776;DTXSID80400706;MFCD03452756;1-(Dihydroxyboryl)-9H-fluoren-9-one;AKOS004116254;AB15466;FT-0621654;F75594

Suppliers and Price of 9-Fluorenone-1-boronic acid

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

American Custom Chemicals Corporation
9-FLUORENONE-1-BORONIC ACID 95.00%
5MG
$ 505.10

Total 12 raw suppliers

Chemical Property of 9-Fluorenone-1-boronic acid

Chemical Property:

Vapor Pressure:2.07E-10mmHg at 25°C
Refractive Index:1.678
Boiling Point:489.8 °C at 760 mmHg
Flash Point:250.1 °C
PSA：57.53000
Density:1.39 g/cm³
LogP:0.57780
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:1
Exact Mass:224.0644743
Heavy Atom Count:17
Complexity:318

Purity/Quality:

99%, ^*data from raw suppliers

9-FLUORENONE-1-BORONIC ACID 95.00% ^*data from reagent suppliers

Safty Information:

Pictogram(s): Xi
Hazard Codes:Xi

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:B(C1=C2C(=CC=C1)C3=CC=CC=C3C2=O)(O)O

Technology Process of 9-Fluorenone-1-boronic acid

There total 2 articles about 9-Fluorenone-1-boronic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 150-46-9
triethyl borate

: 36804-63-4
1-bromo-9H-fluoren-9-one

: 7732-18-5
water

: 194470-10-5
(9-oxo-9H-fluoren-1-yl)boronic acid

Guidance literature:: 1-bromo-9H-fluoren-9-one; With n-butyllithium; In tetrahydrofuran; at -78 ℃; for 0.5h;

triethyl borate; In tetrahydrofuran; at 20 ℃; for 4h;

water; With hydrogenchloride; In diethyl ether;

Reference yield:

: 486-25-9,952573-42-1
9-fluorenone

: 688-74-4
boric acid tributyl ester

: 105563-31-3
lithium 4-methylpiperazin-1-ide

: 194470-10-5
(9-oxo-9H-fluoren-1-yl)boronic acid

Guidance literature:: Yield given. Multistep reaction;
DOI:10.1016/S0040-4039(97)01107-6

Reference yield: 90.0%

: 589-87-7
1,4-bromoiodobenzene

: 194470-10-5
(9-oxo-9H-fluoren-1-yl)boronic acid

: 1-(4-bromophenyl)fluoren-9-one

Guidance literature:: With tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate; In tetrahydrofuran; water; for 24h; Inert atmosphere; Reflux;