12-[2-Benzyloxy-1-(12-oxo-dodecyloxymethyl)-ethoxy]-dodecanal

Base Information

Chemical Name:12-[2-Benzyloxy-1-(12-oxo-dodecyloxymethyl)-ethoxy]-dodecanal
CAS No.:149376-20-5
Molecular Formula:C₃₄H₅₈O₅
Molecular Weight:546.832
Hs Code.:

Synonyms:12-[2-Benzyloxy-1-(12-oxo-dodecyloxymethyl)-ethoxy]-dodecanal

Suppliers and Price of 12-[2-Benzyloxy-1-(12-oxo-dodecyloxymethyl)-ethoxy]-dodecanal

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 12-[2-Benzyloxy-1-(12-oxo-dodecyloxymethyl)-ethoxy]-dodecanal

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 12-[2-Benzyloxy-1-(12-oxo-dodecyloxymethyl)-ethoxy]-dodecanal

There total 5 articles about 12-[2-Benzyloxy-1-(12-oxo-dodecyloxymethyl)-ethoxy]-dodecanal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 149376-19-2
12-[2-Benzyloxy-1-(12-hydroxy-dodecyloxymethyl)-ethoxy]-dodecan-1-ol

: 149376-20-5
12-[2-Benzyloxy-1-(12-oxo-dodecyloxymethyl)-ethoxy]-dodecanal

Guidance literature:: With oxalyl dichloride; dimethyl sulfoxide; triethylamine; In dichloromethane; at -78 ℃; for 2h;
DOI:10.1248/cpb.41.16

Reference yield:

: 5675-51-4
1,12-dodecandiol

: 149376-20-5
12-[2-Benzyloxy-1-(12-oxo-dodecyloxymethyl)-ethoxy]-dodecanal

Guidance literature:: Multi-step reaction with 5 steps

1: 45 percent / CBr₄, Ph₃P / tetrahydrofuran / 0.5 h / Ambient temperature

2: 91 percent / pyridinium p-toluenesulfonate (PPTS) / CH₂Cl₂ / 12 h / Ambient temperature

3: 1.) KH / 1.) DMF, 0 deg C, 2.) DMF, RT, 6h

4: 100 percent / camphorsulfonic acid (CSA) / methanol; CH₂Cl₂ / 5 h / Ambient temperature

5: 96 percent / (COCl)2, DMSO, Et₃N / CH₂Cl₂ / 2 h / -78 °C

With oxalyl dichloride; carbon tetrabromide; camphor-10-sulfonic acid; pyridinium p-toluenesulfonate; potassium hydride; dimethyl sulfoxide; triethylamine; triphenylphosphine; In tetrahydrofuran; methanol; dichloromethane;
DOI:10.1248/cpb.41.16

Reference yield:

: 3344-77-2
12-bromododecanol

: 149376-20-5
12-[2-Benzyloxy-1-(12-oxo-dodecyloxymethyl)-ethoxy]-dodecanal

Guidance literature:: Multi-step reaction with 4 steps

1: 91 percent / pyridinium p-toluenesulfonate (PPTS) / CH₂Cl₂ / 12 h / Ambient temperature

2: 1.) KH / 1.) DMF, 0 deg C, 2.) DMF, RT, 6h

3: 100 percent / camphorsulfonic acid (CSA) / methanol; CH₂Cl₂ / 5 h / Ambient temperature

4: 96 percent / (COCl)2, DMSO, Et₃N / CH₂Cl₂ / 2 h / -78 °C

With oxalyl dichloride; camphor-10-sulfonic acid; pyridinium p-toluenesulfonate; potassium hydride; dimethyl sulfoxide; triethylamine; In methanol; dichloromethane;
DOI:10.1248/cpb.41.16